bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

Base Information

Chemical Name:bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene
CAS No.:78557-92-3
Molecular Formula:C₂₀H₁₅AsMn₂O₄
Molecular Weight:504.134
Hs Code.:

Synonyms:bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

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Chemical Property of bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

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Technology Process of bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

There total 6 articles about bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 62303-61-1
(C₆H₅)Cl₂AsMn(C₅H₅)(CO)2

: 78557-92-3
bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

Guidance literature:: With N,N,N',N'-tetramethylethylene diamine; t-C₄H₉Li; CH₃I; In toluene; addn. of 1 mol-equiv. TMEDA and t-butylLi to soln. of the Mn compd. in toluene (N2, 20°C, color change from yellow to red), addn. of MeI, stirred (90 min, 20°C); evapn. (high. vac.), addn. of CH2Cl2, addn. of silicagel, chromy. (n-pentane/ toluene (1:1), -30°C), recrystn. (n-pentane/ toluene); elem. anal.;

Reference yield: 50.0%

: AsCl(C₅H₅(CO)2MnMn(CO)2C₅H₅)

: 841-76-9
triphenylaluminium

: 78557-92-3
bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

Guidance literature:: In toluene; (inert gas); complex soln. mixed with equimolar amt. of Al compd. soln.; MeOH added, solvent removed, mixed with SiO2, dried, chromd. (pentane/toluene), recrystd. (pentane);
DOI:10.1016/S0022-328X(00)85718-6

Reference yield: 30.0%

: 12079-65-1
cymantrene

: 62303-61-1
(C₆H₅)Cl₂AsMn(C₅H₅)(CO)2

: 78557-92-3
bis[dicarbonyl(η5-cyclopentadienyl)manganese]phenylarsinidene

Guidance literature:: With 18-crown-6; potassium; In tetrahydrofuran; Irradiation (UV/VIS); the soln. of Cp(CO)2Mn/THF was irradiated, Mn-complex, potassium and 18-crown-6 was added at -90°C, warmed to room temp. in 1 h under N2; evapd., toluene was added, filtered (silicagel), chromd. at -30°C, light violet fraction chromd., recrystd. from CH2Cl2/pentane; elem. anal.;