5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin

Base Information

• Chemical Name: 5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin
• CAS No.: 1161736-74-8
• Molecular Formula: C₅₂H₅₉BrN₄Zn
• Molecular Weight: 885.361
• Mol file: 1161736-74-8.mol

Synonyms:5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin

Chemical Property of 5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin

There total 1 articles about 5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

5-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin (1161736-73-7) → 5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin (1161736-74-8)

Guidance literature:

With pyridine; N-Bromosuccinimide; In chloroform; Cooling with ice;

DOI:10.1021/ja901244e

Reference yield: 62.0%

5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin (1161736-74-8) + trimethylsilylacetylene (1066-54-2) → 5-n-butyl-10,20-bis[3,5-di-(tert-butyl)phenyl]-15-trimethylsilylethynyl zinc porphyrin (1161736-71-5)

Guidance literature:

5-bromo-15-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; triethylamine; triphenylphosphine; In toluene; Inert atmosphere;

trimethylsilylacetylene; In toluene; at 40 ℃; Inert atmosphere;

DOI:10.1021/ja901244e

upstream raw materials:

5-n-butyl-10,20-bis[3,5-di(tert-butyl)phenyl] zinc porphyrin

Downstream raw materials:

5-n-butyl-10,20-bis[3,5-di-(tert-butyl)phenyl]-15-trimethylsilylethynyl zinc porphyrin