Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)

Base Information

Chemical Name:Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)
CAS No.:802903-35-1
Molecular Formula:C₁₄H₂₄O
Molecular Weight:208.344
Hs Code.:
Mol file:802903-35-1.mol

Synonyms:Cycloheptanone,2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)

Suppliers and Price of Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)

Chemical Property:

PSA：17.07000
LogP:4.27230

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI)

There total 9 articles about Cycloheptanone, 2-(3Z)-3-hexenyl-2-methyl-, (2S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 55110-62-8
1-(2-phenylethynyl)cycloheptene

: 802903-35-1
(S)-2-((Z)-Hex-3-enyl)-2-methyl-cycloheptanone

Guidance literature:: Multi-step reaction with 9 steps

1.1: aq. KOH; tetrabutylammonium hydrogen sulfate; Shi's chiral ketone / oxone; Na₂EDTA / acetonitrile; various solvent(s); acetate buffer / 2 h / 0 °C

1.2: tetrahydrofuran / 20 °C

2.1: 9-BBN / tetrahydrofuran / 20 °C

2.2: aq. NaOH; aq. H₂O₂ / 3 h / 20 °C

3.1: pyridine; H₂ / Pd/BaSO₄ / 23 h / 760 Torr

4.1: NaH; tetrabutylammonium bromide / tetrahydrofuran / 0.5 h / 20 °C

4.2: tetrahydrofuran / 8 h / Heating

5.1: O₂ / CH₂Cl₂ / 0.03 h / -78 °C

5.2: PPh₃ / CH₂Cl₂ / 2 h / -78 - 20 °C

6.1: N₂H₄; KOH / ethane-1,2-diol / 5 h / 130 - 210 °C

7.1: H₂ / Pd/C / ethanol / 15 h / 760 Torr

8.1: Dess-Martin reagent / CH₂Cl₂ / 0.5 h / 20 °C

9.1: t-BuOK / tetrahydrofuran / 1.5 h / 0 - 20 °C

9.2: tetrahydrofuran / 20 °C

With pyridine; potassium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; Shi's ketone; potassium tert-butylate; tetrabutylammomium bromide; hydrogen; oxygen; tetra(n-butyl)ammonium hydrogensulfate; sodium hydride; Dess-Martin periodane; hydrazine; Oxone; palladium on activated charcoal; Pd-BaSO₄; edetate disodium; In tetrahydrofuran; ethanol; dichloromethane; acetate buffer; ethylene glycol; acetonitrile;
DOI:10.1021/ja045849k

Reference yield:

: 802903-27-1
(1R,2S)-2-Allyl-2-phenylethynyl-cycloheptanol

: 802903-35-1
(S)-2-((Z)-Hex-3-enyl)-2-methyl-cycloheptanone

Guidance literature:: Multi-step reaction with 8 steps

1.1: 9-BBN / tetrahydrofuran / 20 °C

1.2: aq. NaOH; aq. H₂O₂ / 3 h / 20 °C

2.1: pyridine; H₂ / Pd/BaSO₄ / 23 h / 760 Torr

3.1: NaH; tetrabutylammonium bromide / tetrahydrofuran / 0.5 h / 20 °C

3.2: tetrahydrofuran / 8 h / Heating

4.1: O₂ / CH₂Cl₂ / 0.03 h / -78 °C

4.2: PPh₃ / CH₂Cl₂ / 2 h / -78 - 20 °C

5.1: N₂H₄; KOH / ethane-1,2-diol / 5 h / 130 - 210 °C

6.1: H₂ / Pd/C / ethanol / 15 h / 760 Torr

7.1: Dess-Martin reagent / CH₂Cl₂ / 0.5 h / 20 °C

8.1: t-BuOK / tetrahydrofuran / 1.5 h / 0 - 20 °C

8.2: tetrahydrofuran / 20 °C

With pyridine; potassium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; potassium tert-butylate; tetrabutylammomium bromide; hydrogen; oxygen; sodium hydride; Dess-Martin periodane; hydrazine; palladium on activated charcoal; Pd-BaSO₄; In tetrahydrofuran; ethanol; dichloromethane; ethylene glycol;
DOI:10.1021/ja045849k

Reference yield:

: (1R,2S)-2-(3-Hydroxy-propyl)-2-((E)-styryl)-cycloheptanol

: 802903-35-1
(S)-2-((Z)-Hex-3-enyl)-2-methyl-cycloheptanone

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaH; tetrabutylammonium bromide / tetrahydrofuran / 0.5 h / 20 °C

1.2: tetrahydrofuran / 8 h / Heating

2.1: O₂ / CH₂Cl₂ / 0.03 h / -78 °C

2.2: PPh₃ / CH₂Cl₂ / 2 h / -78 - 20 °C

3.1: N₂H₄; KOH / ethane-1,2-diol / 5 h / 130 - 210 °C

4.1: H₂ / Pd/C / ethanol / 15 h / 760 Torr

5.1: Dess-Martin reagent / CH₂Cl₂ / 0.5 h / 20 °C

6.1: t-BuOK / tetrahydrofuran / 1.5 h / 0 - 20 °C

6.2: tetrahydrofuran / 20 °C

With potassium hydroxide; potassium tert-butylate; tetrabutylammomium bromide; hydrogen; oxygen; sodium hydride; Dess-Martin periodane; hydrazine; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; ethylene glycol;
DOI:10.1021/ja045849k