{N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}

Base Information

• Chemical Name: {N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}
• CAS No.: 80612-36-8
• Molecular Formula: C₈H₂₀N*C₁₁H₁₂FeO₃P
• Molecular Weight: 409.289
• Mol file: 80612-36-8.mol

Synonyms:{N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}

Chemical Property of {N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}

There total 3 articles about {N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetraethylammonium hydroxide + Fe(CO)4(dimethylphenylphosphine) (37410-37-0) → {N(CH2CH3)4}(1+)*{HFe(CO)3(P(C6H5)(CH3)2)}(1-)={N(CH2CH3)4}{HFe(CO)3(P(C6H5)(CH3)2)} (80612-36-8)

Guidance literature:

In methanol; Fe-complex treated with 15 equiv of Et4NOH in MeOH, 24 h at room temp.,most of solvent removed under vac. at or slightly below room temp.; extd. with hot toluene, filtered;

DOI:10.1021/ja00368a059

Reference yield:

Dimethyl(phenyl)phosphine (672-66-2) → {N(CH2CH3)4}(1+)*{HFe(CO)3(P(C6H5)(CH3)2)}(1-)={N(CH2CH3)4}{HFe(CO)3(P(C6H5)(CH3)2)} (80612-36-8)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: methanol

In tetrahydrofuran; methanol;

Reference yield:

Fe(CO)4(dimethylphenylphosphine) (37410-37-0) + tetraethylammonium bromide (71-91-0) → {N(CH2CH3)4}(1+)*{HFe(CO)3(P(C6H5)(CH3)2)}(1-)={N(CH2CH3)4}{HFe(CO)3(P(C6H5)(CH3)2)} (80612-36-8)

Guidance literature:

With NaOH; In methanol; treating Fe(CO)4(PMe2Ph) with equimolar amts. of NaOH and (Et4N)Br in methanol (room temp., several h), slowly removing CH3OH (vacuum), vigorous gas evolution; extg. (THF), adding ether, extg. (toluene), filtering, cooling;

upstream raw materials:

Fe(CO)4(dimethylphenylphosphine)

tetraethylammonium bromide

Dimethyl(phenyl)phosphine

Downstream raw materials:

2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}

{N(CH₂CH₃)4}⁽¹⁺⁾*{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)2(C₆H₅))}^(1-)={N(CH₂CH₃)4}{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)2(C₆H₅))}