Cyclohexanone, 4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI)

Base Information

Chemical Name:Cyclohexanone, 4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI)
CAS No.:802622-17-9
Molecular Formula:C₁₄H₂₄O₂
Molecular Weight:224.343
Hs Code.:
Mol file:802622-17-9.mol

Synonyms:Cyclohexanone,4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI)

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Chemical Property of Cyclohexanone, 4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI)

Chemical Property:

PSA：37.30000
LogP:3.10060

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cyclohexanone, 4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI)

There total 11 articles about Cyclohexanone, 4-(hydroxymethyl)-3-methyl-3-(4-methyl-3-pentenyl)-, (3S,4R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141-27-5,96680-15-8
3,7-dimethyl-2,6-octadienal

: 802622-17-9
4-hydroxymethyl-3-methyl-3-(4-methylpent-3-enyl)cyclohexanone

Guidance literature:: Multi-step reaction with 7 steps

1.1: 72 percent / diethyl ether / 1.5 h / -78 °C

2.1: 86 percent / molecular sieves 4 Angstroem; NMO; TPAP / CH₂Cl₂ / 0.5 h / 20 °C

3.1: 93 percent / Huenig base / CH₂Cl₂ / 1 h / -78 °C

4.1: (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; FeBr₃; AgSbF₆ / molecular sieves 5 Angstroem / CH₂Cl₂ / 0.25 h / 20 °C

4.2: CH₂Cl₂ / 30 h / -70 °C

5.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

5.2: tetrahydrofuran / 0.5 h / 0 °C

6.1: LiAlH₄ / tetrahydrofuran / 0.33 h / 0 °C

7.1: HF*pyridine / 6 h / 20 °C

With silver hexafluoroantimonate; ferric(III) bromide; lithium aluminium tetrahydride; n-butyllithium; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; pyridine hydrogenfluoride; N-ethyl-N,N-diisopropylamine; (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; 5A molecular sieve; In tetrahydrofuran; diethyl ether; dichloromethane; 4.2: enantioselective Diels-Alder reaction;

Reference yield:

: 106-26-3,96680-15-8
cis-3,7-dimethyl-2,6-octadienal

: 802622-17-9
4-hydroxymethyl-3-methyl-3-(4-methylpent-3-enyl)cyclohexanone

Guidance literature:: Multi-step reaction with 7 steps

1.1: 98 percent / diethyl ether / 1.5 h / -78 °C

2.1: 89 percent / molecular sieves 4 Angstroem; NMO; TPAP / CH₂Cl₂ / 0.5 h / 20 °C

3.1: 81 percent / Huenig base / CH₂Cl₂ / 1 h / -78 °C

4.1: (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; FeBr₃; AgSbF₆ / molecular sieves 5 Angstroem / CH₂Cl₂ / 0.25 h / 20 °C

4.2: CH₂Cl₂ / 30 h / -70 °C

5.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

5.2: tetrahydrofuran / 0.5 h / 0 °C

6.1: LiAlH₄ / tetrahydrofuran / 0.33 h / 0 °C

7.1: HF*pyridine / 6 h / 20 °C

With silver hexafluoroantimonate; ferric(III) bromide; lithium aluminium tetrahydride; n-butyllithium; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; pyridine hydrogenfluoride; N-ethyl-N,N-diisopropylamine; (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; 5A molecular sieve; In tetrahydrofuran; diethyl ether; dichloromethane; 4.2: enantioselective Diels-Alder reaction;

Reference yield:

: 27575-61-7
(3Z)-4,8-dimethylnona-3,7-dien-2-one

: 802622-17-9
4-hydroxymethyl-3-methyl-3-(4-methylpent-3-enyl)cyclohexanone

Guidance literature:: Multi-step reaction with 5 steps

1.1: 81 percent / Huenig base / CH₂Cl₂ / 1 h / -78 °C

2.1: (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; FeBr₃; AgSbF₆ / molecular sieves 5 Angstroem / CH₂Cl₂ / 0.25 h / 20 °C

2.2: CH₂Cl₂ / 30 h / -70 °C

3.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

3.2: tetrahydrofuran / 0.5 h / 0 °C

4.1: LiAlH₄ / tetrahydrofuran / 0.33 h / 0 °C

5.1: HF*pyridine / 6 h / 20 °C

With silver hexafluoroantimonate; ferric(III) bromide; lithium aluminium tetrahydride; n-butyllithium; pyridine hydrogenfluoride; N-ethyl-N,N-diisopropylamine; (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; 5A molecular sieve; In tetrahydrofuran; dichloromethane; 2.2: enantioselective Diels-Alder reaction;