dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone

Base Information

• Chemical Name: dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone
• CAS No.: 123883-86-3
• Molecular Formula: C₁₃H₁₆O₂Se
• Molecular Weight: 283.229
• Mol file: 123883-86-3.mol

Synonyms:dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone

Chemical Property of dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone

There total 5 articles about dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2,2-dimethylpent-4-enoic acid (16386-93-9) + diphenyl diselenide (1666-13-3) → dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone (123883-86-3)

Guidance literature:

With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; In acetonitrile; at 20 ℃; for 4h; Irradiation; Green chemistry;

DOI:10.1021/acs.orglett.8b03738

Reference yield: 70.0%

diphenyl diselenide (1666-13-3) + N-(1-oxo-2,2-dimethyl-4-pentenyl)acetamide (123883-66-9) → dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone (123883-86-3)

Guidance literature:

With ammonium persulfate; In acetonitrile; at 25 ℃; for 1h;

DOI:10.1021/jo00289a010

Reference yield: 10.0%

2,2-dimethylpent-4-enenitrile (2978-30-5) + diphenyl diselenide (1666-13-3) → dihydro-3,3-dimethyl-5-<(phenylseleno)methyl>-2(3H)-furanone (123883-86-3) + 2,2-dimethyl-4-hydroxy-5-(phenylseleno)pentanenitrile (127560-80-9)

Guidance literature:

With ammonium persulfate; trifluorormethanesulfonic acid; In 1,4-dioxane; water; at 70 ℃;

DOI:10.1016/S0040-4020(01)89150-X

upstream raw materials:

2,2-dimethylpent-4-enenitrile

diphenyl diselenide

N-(1-oxo-2,2-dimethyl-4-pentenyl)acetamide

2,2-dimethylpent-4-enoyl chloride