1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

Base Information

Chemical Name:1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide
CAS No.:78089-53-9
Molecular Formula:C₁₅H₁₃F₃NOP
Molecular Weight:311.243
Hs Code.:

Synonyms:1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

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Technology Process of 1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

There total 6 articles about 1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: benzazaphosphole

: 78089-70-0
N-<3-(Trifluoromethyl)phenyl>-P-(α-chloro-2-tolyl)-P-methylphosphinamide

: 148116-22-7
1,5-Diazabicyclo[5.4.0]undec-5-ene

: 78089-53-9
1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

Guidance literature:: In tetrahydrofuran; diethyl ether; dichloromethane;

Reference yield: 50.0%

: 78089-70-0
N-<3-(Trifluoromethyl)phenyl>-P-(α-chloro-2-tolyl)-P-methylphosphinamide

: 78089-53-9
1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran;
DOI:10.1021/jo00330a021

Reference yield:

: 615-37-2
ortho-methylphenyl iodide

: 78089-53-9
1-Methyl-2-<3-(trifluoromethyl)phenyl>-2,3-dihydro-1H-2,1-benzazaphosphole 1-Oxide

Guidance literature:: Multi-step reaction with 5 steps

1: NiCl₂ / 2.5 h / 160 - 170 °C

2: PCl₅ / benzene / 1 h / Heating

3: Cl₂ / CCl₄ / 1.5 h / Heating; Irradiation

4: diethyl ether

5: 50 percent / 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / tetrahydrofuran

With phosphorus pentachloride; chlorine; 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel dichloride; In tetrahydrofuran; tetrachloromethane; diethyl ether; benzene;
DOI:10.1021/jo00330a021