{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

Base Information

Chemical Name:{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate
CAS No.:56557-01-8
Molecular Formula:C₄IrO₄*C₃₆H₃₀NP₂
Molecular Weight:842.85
Hs Code.:

Synonyms:{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

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Chemical Property of {bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

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Technology Process of {bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

There total 6 articles about {bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 117678-68-9
dodecacarbonyltetrairidium

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 56557-01-8
{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

Guidance literature:: With carbon monoxide; sodium anthracene; In tetrahydrofuran; (CO), soln. of the Na-anthracene (excess 5:1) added dropwise over a period of 1 h to a soln. of the Ir-complex, decanted, added dropwise to a stirred soln. of (PPN)Cl in isopropanol and water; concd. in vacuo until most of the isopropanol was removed, collected byfiltration, washed with isopropanol and toluene, vacuum dried, recrystd. twice from THF/toluene;

Reference yield: 69.0%

: iridium(III) chloride hydrate

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 56557-01-8
{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

Guidance literature:: With potassium hydroxide; carbon monoxide; In N,N-dimethyl-formamide; byproducts: CO3(2-), H2O, Cl(1-); (CO), Ir-compd. stirred at room temp. with powdered KOH suspended in DMF (about 24 h), decanted from the KOH, added dropwise to a stirred soln.of (PPN)Cl in isopropanol and water; concd. in vacuo until most of the isopropanol was removed, collected byfiltration, washed with isopropanol, vacuum dried, recrystd. by dissolution in a minimum of THF, addition of isopropanol, concn. in vacuo untilTHF was eliminated;

Reference yield: 61.0%

: 2(N(P(C₆H₅)3)2)⁽¹⁺⁾*FeIr₄^(2-)*15CO*2C₄H₈O=(N(P(C₆H₅)3)2)2(FeIr₄(CO)15)*2C₄H₈O

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 56557-01-8
{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

: bis(triphenylphosphine)iminium 1,2;1,4;2,4-tri-μ-carbonyl-1,1,2,2,3,3,3,4,4-nonacarbonyl-tetrahedro-1,2,3-tri-iridium-4-ferrate

Guidance literature:: With CO; In tetrahydrofuran; dissolution of Fe-Ir-compd. in THF, evacuation of Schlenk tube, refilling with CO, stirring at room temp. for 4 d; filtn., washing with MeOH, addn. of (N(PPh3)2)Cl to the filtrate, removal of solvent under vac., dissolution in THF, filtn. (byproduct), mother liquor reduced in vol. in vacuo, pptn., filtn., washing with 2-propanol, drying in vacuo, elem. anal.;