6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

Base Information

Chemical Name:6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol
CAS No.:380366-30-3
Molecular Formula:C₃₂H₅₀O₈
Molecular Weight:562.744
Hs Code.:

Synonyms:6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

Chemical Property:

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Technology Process of 6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

There total 1 articles about 6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 106-95-6
allyl bromide

: 153996-48-6
2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

: 380366-30-3
6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

Guidance literature:: With potassium iodide; silver(l) oxide; In N,N-dimethyl-formamide; at 0 ℃; for 1.5h;
DOI:10.1021/jo015840q

Reference yield: 68.0%

: 380366-30-3
6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

: 579493-70-2
6-O-allyl-2,3-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

Guidance literature:: With pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; In methanol; dichloromethane; at 45 ℃; for 1.16667h;
DOI:10.1016/j.carres.2003.06.002

Reference yield:

: 380366-30-3
6-O-allyl-2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

: 380366-31-4
(3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->6)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-D-myo-inositol

Guidance literature:: Multi-step reaction with 6 steps

1.1: 3.86 g / K₂CO₃ / methanol / 20 h / 60 °C

2.1: NaH / dimethylformamide / 3 h / 0 °C

3.1: 3.0 g / CSA / methanol / 8 h / 20 °C

4.1: 92 percent / NaH / dimethylformamide / 2 h / 20 °C

5.1: DBU / (PPh₃)3RhCl / ethanol / 1 h / Heating

5.2: 95 percent / 1N HCl / acetone / 0.17 h / Heating

6.1: 70 percent / 4 Angstroem MS; TMSOTf / CH₂Cl₂ / 0.33 h / 0 °C

With trimethylsilyl trifluoromethanesulfonate; 4 Angstroem MS; camphor-10-sulfonic acid; sodium hydride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; Wilkinson's catalyst; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo015840q