benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

Base Information

Chemical Name:benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine
CAS No.:863555-93-5
Molecular Formula:C₅₉H₅₇NO₈
Molecular Weight:908.103
Hs Code.:

Synonyms:benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

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Chemical Property of benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

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Technology Process of benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

There total 3 articles about benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: (2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-acetaldehyde

: 3287-99-8,39110-74-2,108321-65-9
benzylamine hydrochloride

: 863555-93-5
benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

Guidance literature:: benzylamine hydrochloride; With sodium tris(acetoxy)borohydride; acetic acid; In 1,2-dichloro-ethane; at 20 ℃;

(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-acetaldehyde; With sodium tris(acetoxy)borohydride; acetic acid; In 1,2-dichloro-ethane; at 20 ℃;
DOI:10.1016/j.tetlet.2005.05.139

Reference yield:

: 2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethanol

: 863555-93-5
benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: 73 percent / Dess-Martin reagent / CH₂Cl₂ / 5 h / 20 °C

2.1: AcOH; NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

2.2: 59 percent / AcOH; NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

With sodium tris(acetoxy)borohydride; Dess-Martin periodane; acetic acid; In dichloromethane; 1,2-dichloro-ethane; 1.1: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2005.05.139

Reference yield:

: 74292-20-9,142128-92-5
(S)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl

: 863555-93-5
benzyl-bis-[2-(2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-3-yl)-ethyl]-amine

Guidance literature:: Multi-step reaction with 3 steps

1.1: 77 percent / t-BuLi; BF₃*OEt₂ / 1 h / -78 °C

2.1: 73 percent / Dess-Martin reagent / CH₂Cl₂ / 5 h / 20 °C

3.1: AcOH; NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

3.2: 59 percent / AcOH; NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

With boron trifluoride diethyl etherate; tert.-butyl lithium; sodium tris(acetoxy)borohydride; Dess-Martin periodane; acetic acid; In dichloromethane; 1,2-dichloro-ethane; 2.1: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2005.05.139