{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

Base Information

Chemical Name:{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium
CAS No.:81899-94-7
Molecular Formula:C₂₂H₂₂N₄OTi
Molecular Weight:406.323
Hs Code.:

Synonyms:{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

Suppliers and Price of {7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

There total 1 articles about {7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (C₂₂H₂₂N₄)Ti(CO₂)Re(CO)(NO)(C₅(CH₃)5)⁽¹⁺⁾*BF₄^(1-)=((C₂₂H₂₂N₄)Ti(CO₂)Re(CO)(NO)(C₅(CH₃)5))(BF₄)

: 2325-27-1
N-phenyltriphenyliminophosphorane

: 81899-94-7
{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

: (C₅(CH₃)5)Re(CNC₆H₅)2(NO)⁽¹⁺⁾*BF₄^(1-)=((C₅(CH₃)5)Re(CNC₆H₅)2(NO))(BF₄)

Guidance literature:: In dichloromethane; byproducts: OP(C6H5)3; N2 atmosphere; stirring of the Re-Ti complex and the phosphine imide in CH2Cl2 at 20°C for 4 h; evapn. under vac., extg. with CH3CN, evapn. under vac.;

Reference yield: 94.0%

: 19172-47-5,94367-93-8
Lawessons reagent

: 81899-94-7
{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

: 144269-88-5
(C₂₂H₂₂N₄)Ti(OPS₂C₆H₄OCH₃)*CH₂Cl₂

Guidance literature:: With CH₂Cl₂; In dichloromethane; N2 atmosphere; addn. of Lawesson's reagent to a soln. of the Ti complex in CH2Cl2, stirring for 20 min at 20°C; concn. under vac., pptg. by addn. of pentane, recrystn. from CH2Cl2/pentane, addn. of hexane, freezing in a liquid N2 bath, warming to room temp., decantation, elem. anal.;

Reference yield: 85.0%

: 81899-94-7
{7,16-dihydro-6,8,15,17-tetramethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinediato}oxotitanium

: 434-45-7
2,2,2-Trifluoroacetophenone

: (C₂₂H₂₂N₄)Ti(OC(CF₃)(C₆H₅)O)*CH₂Cl₂

Guidance literature:: With CH₂Cl₂; In dichloromethane; N2 atmosphere; addn. of the acetophenone to a soln. of the Ti complex in CH2Cl2, stirring for 1 h; evapn. under vac., recrystn. from CH2Cl2/pentane, addn. of hexane, freezing in a liquid N2 bath, warming to room temp., decantation, elem. anal.;