5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin

Base Information

• Chemical Name: 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin
• CAS No.: 102575-55-3
• Molecular Formula: C₅₂H₄₂N₄O₁₂S₄*4Na
• Molecular Weight: 1135.15
• Mol file: 102575-55-3.mol

Synonyms:5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin

Chemical Property of 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin

There total 1 articles about 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

<5,10,15,20-tetrakis(2,6-dimethylphenyl)porphinato>zinc(II) (91947-22-7) → 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin (102575-55-3)

Guidance literature:

With sodium hydroxide; sulfuric acid; at 100 ℃; for 4h;

DOI:10.1021/ja00275a033

Reference yield: 92.0%

water (7732-18-5) + nickel(II) acetate tetrahydrate (6018-89-9) + 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin (102575-55-3) → nickel(II)-tetrasodium-5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphyrin*6H2O

Guidance literature:

water; nickel(II) acetate tetrahydrate; 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphirin; for 12h; Inert atmosphere; Reflux;

With Amberlite IR 120 Na+ form ion exchange resin;

DOI:10.1002/anie.202103157

Reference yield:

ferrous(II) sulfate heptahydrate + tetrasodium 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphyrin (102575-55-3) → tetrasodium diaqua[5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphyrinato]iron(III) hemisulfate (102588-49-8)

Guidance literature:

With NaOH; In water; porphyrin and FeSO4*7H2O in water were heated to reflux for 20 h, during reaction time the pH was adjusted three times to 5-8 with 1 N NaOH; followed by UV-vis spectroscopy; NaOH added (pH 12-13), chilled, filtered, passed over Dowex 50 WX-8 (H(1+)), NaOH added (pH 6), evapd., dissolved (heating and sonication) in MeOH, acidified (HCl), chromd. twice over Sephadex LH 20 (MeOH), repptd. with acetone from H2O; elem. anal.;

DOI:10.1021/ja00275a033

upstream raw materials:

<5,10,15,20-tetrakis(2,6-dimethylphenyl)porphinato>zinc(II)

Downstream raw materials:

tetrasodium diaqua[5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphyrinato]iron(III) hemisulfate