methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

Base Information

Chemical Name:methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate
CAS No.:865375-33-3
Molecular Formula:C₁₅H₁₈N₄O₄
Molecular Weight:318.332
Hs Code.:

Synonyms:methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

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Chemical Property of methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

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Technology Process of methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

There total 9 articles about methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: (1S,2R)-1-Benzyloxycarbonylamino-2-(2-methanesulfonyl-ethyl)-cyclopropanecarboxylic acid methyl ester

: 865375-33-3
methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

Guidance literature:: With sodium azide; sodium iodide; In N,N-dimethyl-formamide; for 18h; Heating;
DOI:10.1055/s-2005-870007

Reference yield: 95.0%

: 161111-16-6
Methyl (1S,2R)-1--2-(2-(methanesulfonyloxy)ethyl)cyclopropanecarboxylate

: 865375-33-3
methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

Guidance literature:: With sodium azide; sodium iodide; In N,N-dimethyl-formamide; for 18h; Heating;
DOI:10.1055/s-2005-870007

Reference yield:

: (1S,6R)-1-Isocyanato-3-oxa-bicyclo[4.1.0]heptan-2-one

: 865375-33-3
methyl (1S,2S)-2-(2-azidoethyl)-1-{[(benzyloxy)carbonyl]amino}cyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: toluene / Heating

2: lithium hydroxide / tetrahydrofuran / 20 °C

3: potassium carbonate / N,N-dimethyl-formamide; acetonitrile

4: TEA; sodium hydrogencarbonate / dichloromethane / 1 h

5: sodium azide; sodium iodide / N,N-dimethyl-formamide / 18 h / Heating

With lithium hydroxide; sodium azide; TEA; sodium hydrogencarbonate; potassium carbonate; sodium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1055/s-2005-870007