IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)
• CAS No.: 104453-06-7
• Molecular Formula: C₄₁H₄₀Cl₂IrP₃
• Molecular Weight: 888.816
• Mol file: 104453-06-7.mol

Synonyms:IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

Chemical Property of IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

There total 4 articles about IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

IrCl3(tripod) (104453-05-6,34397-69-8) → IrHCl2(CH3C(CH2P(C6H5)2)3) (104453-06-7)

Guidance literature:

With H₂; In methanol; purging H2 (room temp., 5 h, pptn.); mixt. with starting complex (5%) not sepd., detd. by (31)P-NMR;

DOI:10.1016/0022-328X(85)80351-X

Reference yield: 41.0%

2-methoxy-ethanol (109-86-4,95507-80-5) + Ir(1,1,1-tris(diphenylphosphinomethyl)ethane)Cl3 (104453-05-6,34397-69-8) → Ir(1,1,1-tris(diphenylphosphinomethyl)ethane)Cl2H (104453-06-7)

Guidance literature:

for 12h; Reflux; Inert atmosphere;

DOI:10.1021/ic401835d

Reference yield:

IrH2(CH3C(CH2P(C6H5)2)3)(SC6H4C2H5) (150266-23-2) → Ir(1,1,1-tris(diphenylphosphinomethyl)ethane)Cl2H (104453-06-7)

Guidance literature:

With HCl; In dichloromethane-d2; byproducts: 2-ethylbenzenethiol, H2; 20°C, excess of gaseous HCl; NMR, GC/MS;

DOI:10.1021/ja00069a061

upstream raw materials:

IrCl₃(tripod)

IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)

2-methoxy-ethanol

Ir(1,1,1-tris(diphenylphosphinomethyl)ethane)Cl₃

Downstream raw materials:

IrCl₃(tripod)