O-ethyl S-4-methoxybenzyl carbonodithioate

Base Information

• Chemical Name: O-ethyl S-4-methoxybenzyl carbonodithioate
• CAS No.: 18357-74-9
• Molecular Formula: C₁₁H₁₄O₂S₂
• Molecular Weight: 242.363
• Mol file: 18357-74-9.mol

Synonyms:O-ethyl S-4-methoxybenzyl carbonodithioate

Chemical Property of O-ethyl S-4-methoxybenzyl carbonodithioate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of O-ethyl S-4-methoxybenzyl carbonodithioate

There total 2 articles about O-ethyl S-4-methoxybenzyl carbonodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

potassium ethyl xanthogenate (140-89-6) + p-methoxybenzyl chloride (824-94-2) → O-ethyl S-4-methoxybenzyl carbonodithioate (18357-74-9)

Guidance literature:

In acetone; at 20 ℃; for 21h; stereoselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.5b01344

Reference yield:

→ O-ethyl S-4-methoxybenzyl carbonodithioate (18357-74-9)

Guidance literature:

4-Chlormethylanisol, NaSC(=S)OEt;

Reference yield: 67.0%

O-ethyl S-4-methoxybenzyl carbonodithioate (18357-74-9) + ethyl (3,3,3-trifluoro-1-(methylsulfonyl)prop-1-en-2-yl) carbonate → (Z)-ethyl [1,1,1-trifluoro-4-(4-methoxyphenyl)but-2-en-2-yl] carbonate

Guidance literature:

With di-tert-butyl peroxide; In chlorobenzene; for 8h; stereoselective reaction; Reflux; Inert atmosphere;

DOI:10.1021/acs.orglett.5b01344

upstream raw materials:

potassium ethyl xanthogenate

p-methoxybenzyl chloride

Downstream raw materials:

1,1,1-trifluoro-4-(4-methoxy-phenyl)-butan-2-one