chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate

Base Information

• Chemical Name: chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate
• CAS No.: 64561-63-3
• Molecular Formula: C₅₄H₅₂ClOsP₄*F₆P
• Molecular Weight: 1195.52
• Mol file: 64561-63-3.mol

Synonyms:chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate

Chemical Property of chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate

There total 6 articles about chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

ammonium hexafluorophosphate + diammonium hexachloroosmate(IV) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → chlorodi-(1,3-bisdiphenylphosphinopropane)osmium(II) hexafluorophosphate (64561-63-3)

Guidance literature:

In 2-methoxy-ethanol; Ar-atmosphere; refluxing Os-complex with ligand for 6 h, cooling, addn. of NH4PF6 in EtOH; collection (filtration), drying (vac.), recrystn. (CH2Cl2/i-PrOH); recrystn.;

DOI:10.1021/ic9605579

Reference yield: 60.0%

ammonium hexafluorophosphate + trans-[OsCl2(1,3-bis(diphenylphosphino)propane)2] (64561-61-1) → [OsCl(1,3-bis(diphenylphosphino)propane)2]PF6 (64561-63-3)

Guidance literature:

In tert-butyl alcohol; refluxing Os-complex with slight excess of NH4PF6 (72 h, pptn.); recrystn. (THF/EtOH); elem. anal.;

DOI:10.1016/S0020-1693(00)93827-1

Reference yield: 20.0%

ammonium hexafluorophosphate + diammonium hexachloroosmate(IV) → [OsCl(1,3-bis(diphenylphosphino)propane)2]PF6 (64561-63-3)

Guidance literature:

With 1,3-bis(diphenylphosphino)propane; In water; tert-butyl alcohol; refluxing Os-complex (in H2O) with 3 equiv. of ligand (in t-BuOH) for 48h, filtration, addn. of NH4PF6 (pptn.); recrystn. (THF/EtOH);

DOI:10.1016/S0020-1693(00)93827-1

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

trans-[OsCl₂(1,3-bis(diphenylphosphino)propane)2]

Downstream raw materials:

trans-[OsCl(η(2)-H2)(1,3-bis(diphenylphosphino)propane)2][PF6] * i-PrOH

trans-[OsCl(CO)(1,3-bis(diphenylphosphino)propane)2]PF₆