oxo(acetato)molybdenum(V) tetraphenylporphyrin

Base Information

• Chemical Name: oxo(acetato)molybdenum(V) tetraphenylporphyrin
• CAS No.: 77320-98-0
• Molecular Formula: C₄₆H₃₁MoN₄O₃
• Molecular Weight: 783.717
• Mol file: 77320-98-0.mol

Synonyms:oxo(acetato)molybdenum(V) tetraphenylporphyrin

Chemical Property of oxo(acetato)molybdenum(V) tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of oxo(acetato)molybdenum(V) tetraphenylporphyrin

There total 3 articles about oxo(acetato)molybdenum(V) tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

Mo(V)O(tpp)OCH3 (74751-79-4) → oxo(acetato)molybdenum(V) tetraphenylporphyrin (77320-98-0)

Guidance literature:

With CH₃COOH; In dichloromethane; Mo-complex was dissolved in CH3COOH-CH2Cl2, refluxed for 3 h, soln. wasevapd. to dryness in vac. at room temp.; solid was dissolved in CH3COOH, allowed to stand in a freezer overnight, collected, washed with CH3COOH-hexane, dried in vac. at 80°C; elem. anal.;

DOI:10.1021/ic50221a060

Reference yield:

μ-O-bis{oxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)} → oxo(acetato)molybdenum(V) tetraphenylporphyrin (77320-98-0)

Guidance literature:

With CH₃COOH; In dichloromethane; Mo-complex was dissolved in CH3COOH-CH2Cl2, refluxed for 3 h, soln. wasevapd. to dryness in vac. at room temp.; solid was dissolved in CH3COOH, allowed to stand in a freezer overnight, collected, washed with CH3COOH-hexane, dried in vac. at 80°C;

DOI:10.1021/ic50221a060

Reference yield:

(5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(IV) (33519-60-7) → acetato(5,10,15,20-tetraphenylporphinato)oxomolibdenum(V) (77320-98-0)

Guidance literature:

In not given; Electrochem. Process; at 0 V (SCE) under anaerobic condition for 12 h;

DOI:10.1246/bcsj.54.452

upstream raw materials:

(5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(IV)

Mo(V)O(tpp)OCH₃

Downstream raw materials:

oxo(nitrito)molybdenum(V) tetraphenylporphyrin