β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

Base Information

Chemical Name:β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose
CAS No.:107961-16-0
Molecular Formula:C₂₁H₂₆O₉S
Molecular Weight:454.498
Hs Code.:

Synonyms:β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

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Chemical Property of β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

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Technology Process of β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

There total 6 articles about β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.3%

: 6773-29-1
dimethyl diazomalonate

: 107961-05-7
β-1-deoxy-1-C-(phenylthio)-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

: 107961-16-0
β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

Guidance literature:: rhodium(II) acetate; In dichloromethane; for 3h; Heating;
DOI:10.1021/ja00244a024

Reference yield: 28.0%

: 6773-29-1
dimethyl diazomalonate

: 107961-06-8
α-1-deoxy-1-C-(phenylthio)-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

: 107961-16-0
β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

Guidance literature:: rhodium(II) acetate; In dichloromethane; for 7h; Heating;
DOI:10.1021/ja00244a024

Reference yield:

: 62410-12-2
1,5-di-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranose

: 107961-16-0
β-1-deoxy-1-C-<(phenylthio)bis(methoxycarbonyl)methyl>-2,3-O-isopropylidene-5-O-acetyl-D-ribofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 35.1 percent / boron trifluoride etherate / CH₂Cl₂ / 1 h / Ambient temperature

2: 34.3 percent / rhodium(II) acetate / CH₂Cl₂ / 3 h / Heating

With boron trifluoride diethyl etherate; rhodium(II) acetate; In dichloromethane;
DOI:10.1021/ja00244a024