benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Base Information

Chemical Name:benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside
CAS No.:82186-20-7
Molecular Formula:C₄₃H₅₀O₁₆
Molecular Weight:822.86
Hs Code.:

Synonyms:benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Suppliers and Price of benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

There total 8 articles about benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 82186-19-4
benzyl 6-O-acetyl-2,4-di-O-benzyl-α-D-glucopyranoside

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 82186-20-7
benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Guidance literature:: With 4 A molecular sieve; mercury dibromide; In 1,2-dichloro-ethane; at 20 ℃; for 2.5h;
DOI:10.1016/S0008-6215(82)80007-4

Reference yield:

: 186697-04-1
benzyl 4,6-O-benzylidene-α-D-glucopyranoside

: 82186-20-7
benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Bu₂SnO / 1.) benzene, MeOH, reflux, 2.5 h; 2.) DMF, 100-120 deg C, 3.5 h

2: 53 percent / LiAlH₄, AlCl₃ / diethyl ether; CH₂Cl₂ / 2 h / Heating

3: 82 percent / pyridine / CH₂Cl₂ / 2 h / -15 - -10 °C

4: 73 percent / powdered molecular sieve 4 A, HgBr₂ / 1,2-dichloro-ethane / 2.5 h / 20 °C

With pyridine; lithium aluminium tetrahydride; aluminium trichloride; 4 A molecular sieve; di(n-butyl)tin oxide; mercury dibromide; In diethyl ether; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1016/S0008-6215(82)80007-4

Reference yield:

: 34246-23-6
benzyl D-glucopyranoside

: 82186-20-7
benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) TsOH*H₂O; 2.) Et₃N / dimethylformamide / 2 h / 40 - 45 °C

2: 1.) Bu₂SnO / 1.) benzene, MeOH, reflux, 2.5 h; 2.) DMF, 100-120 deg C, 3.5 h

3: 53 percent / LiAlH₄, AlCl₃ / diethyl ether; CH₂Cl₂ / 2 h / Heating

4: 82 percent / pyridine / CH₂Cl₂ / 2 h / -15 - -10 °C

5: 73 percent / powdered molecular sieve 4 A, HgBr₂ / 1,2-dichloro-ethane / 2.5 h / 20 °C

With pyridine; lithium aluminium tetrahydride; aluminium trichloride; 4 A molecular sieve; di(n-butyl)tin oxide; toluene-4-sulfonic acid; triethylamine; mercury dibromide; In diethyl ether; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(82)80007-4