Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid

Base Information

• Chemical Name: Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid
• CAS No.: 136945-16-9
• Molecular Formula: C₄₄H₅₃NO₁₄
• Molecular Weight: 819.903
• Mol file: 136945-16-9.mol

Synonyms:Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid

Chemical Property of Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid

There total 22 articles about Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-[acetyl-(2,2,2-trichloro-ethoxycarbonyl)-amino]-6-((2S,3S,4S,5R,6R)-2-allyloxy-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester (187456-09-3) → Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid (136945-16-9)

Guidance literature:

With acetic acid; zinc; for 5h;

DOI:10.1016/S0008-6215(96)00237-6

Reference yield: 85.0%

acetic anhydride (108-24-7) + allyl O-<3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl>-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside (136945-15-8) → Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid (136945-16-9)

Guidance literature:

With zinc; for 5h; Ambient temperature;

DOI:10.1016/S0008-6215(96)00237-6

Reference yield: 83.0%

allyl 3,4,6-tri-O-acetyl-2-deoxy-2-diglycolylimido-β-D-glucopyranosyl-(1->2)-2,3,6-tri-O-benzyl-α-D-mannopyranoside (871116-00-6) → Allyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid (136945-16-9)

Guidance literature:

allyl 3,4,6-tri-O-acetyl-2-deoxy-2-diglycolylimido-β-D-glucopyranosyl-(1->2)-2,3,6-tri-O-benzyl-α-D-mannopyranoside; With potassium hydroxide; In ethanol; for 4h; Heating;

With pyridine; acetic anhydride; at 20 ℃;

DOI:10.1002/ejoc.200500107

upstream raw materials:

allyl O-<3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl>-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside

acetic anhydride

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-[acetyl-(2,2,2-trichloro-ethoxycarbonyl)-amino]-6-((2S,3S,4S,5R,6R)-2-allyloxy-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

allyl 3,4,6-tri-O-acetyl-2-deoxy-2-diglycolylimido-β-D-glucopyranosyl-(1->2)-2,3,6-tri-O-benzyl-α-D-mannopyranoside

Downstream raw materials:

O-(2-Acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-1-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranose

8-Methoxycarbonyloctyl-O-(2-acetamido-3,4,6-tri-O-acetyl-2-desoxy-β-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-acetyl-α-D-mannopyranosyl)-(1->3)-2,4,6-tri-O-benzyl-β-D-mannopyranosid