C₆₉H₈₆Br₂O₁₀Si

Base Information

Chemical Name:C₆₉H₈₆Br₂O₁₀Si
CAS No.:876288-93-6
Molecular Formula:C₆₉H₈₆Br₂O₁₀Si
Molecular Weight:1263.33
Hs Code.:

C<sub>69</sub>H<sub>86</sub>Br<sub>2</sub>O<sub>10</sub>Si

Synonyms:C₆₉H₈₆Br₂O₁₀Si

Suppliers and Price of C₆₉H₈₆Br₂O₁₀Si

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₆₉H₈₆Br₂O₁₀Si

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of C₆₉H₈₆Br₂O₁₀Si

There total 29 articles about C₆₉H₈₆Br₂O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 876288-92-5
C₆₉H₈₄Br₂O₁₀Si

: 876288-93-6
C₆₉H₈₆Br₂O₁₀Si

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at 0 ℃; for 4h;
DOI:10.1016/j.tetlet.2005.11.085

Reference yield:

: 876288-91-4
2-{2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-1-hydroxy-ethyl}-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-decahydro-1,5-dioxa-benzocycloocten-3-ol

: 876288-93-6
C₆₉H₈₆Br₂O₁₀Si

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / PPTS / benzene / 1.5 h / 80 °C

2: 100 percent / DIBAL / hexane; CH₂Cl₂ / 3 h / 0 - 10 °C

With pyridinium p-toluenesulfonate; diisobutylaluminium hydride; In hexane; dichloromethane; benzene;
DOI:10.1016/j.tet.2006.05.014

Reference yield:

: 876288-75-4
(1R,3S,4R,6Z,9S,11S)-3-hydroxymethyl-11-phenyl-2,10,12-trioxabicyclo[7.4.0]tridecan-6-en-4-ol

: 876288-93-6
C₆₉H₈₆Br₂O₁₀Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: 98 percent / NaH; TBAI / tetrahydrofuran / 0.38 h / 0 - 25 °C

2.1: 98 percent / aq. HCl / tetrahydrofuran / 21 h / 25 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 0.25 h / -78 °C

4.1: 17.5 mg / 2,6-lutidine / CH₂Cl₂ / 1 h / -78 - 0 °C

5.1: BuLi / tetrahydrofuran / 0.17 h / -78 °C

5.2: 99 percent / tetrahydrofuran / 3 h / -78 - 24 °C

6.1: Cp₂ZrCl₂; DIBAL / tetrahydrofuran; hexane / 0.5 h / 55 °C

6.2: 86 percent / I₂ / tetrahydrofuran; hexane / 0.25 h / 0 °C

7.1: 40 percent / CrCl₂; NiCl₂ / dimethylsulfoxide / 25 h / 25 °C

8.1: VO(acac)2; TBHP / toluene / 2.5 h / 0 °C

8.2: 91 percent / dimethylsulfide / toluene / 0.5 h / 24 °C

9.1: 100 percent / 2,6-lutidine / tetrahydrofuran / 0.17 h / 0 - 25 °C

10.1: 97 percent / DDQ; pH 7 buffer / CH₂Cl₂ / 0.83 h / 0 °C / pH 7

11.1: CSA / CH₂Cl₂ / 0.42 h / 0 °C

11.2: 80 percent / triethylamine / CH₂Cl₂ / 0.5 h / 0 - 25 °C

12.1: 61 percent / (COCl)2; triethylamine; DMSO / CH₂Cl₂ / 1.25 h / -78 - 0 °C

13.1: 71 percent / HF*Py; pyridine / tetrahydrofuran / 144 h / 25 °C

14.1: 61 percent / NaBH₄ / methanol / 0.25 h / 0 °C

15.1: 89 percent / PPTS / benzene / 1.5 h / 80 °C

16.1: 100 percent / DIBAL / hexane; CH₂Cl₂ / 3 h / 0 - 10 °C

With pyridine; 2,6-dimethylpyridine; chromium dichloride; hydrogenchloride; tert.-butylhydroperoxide; sodium tetrahydroborate; n-butyllithium; zirconocene dichloride; oxalyl dichloride; bis(acetylacetonate)oxovanadium; pH 7 buffer; camphor-10-sulfonic acid; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; pyridine hydrogenfluoride; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; nickel dichloride; In tetrahydrofuran; methanol; hexane; dichloromethane; dimethyl sulfoxide; toluene; benzene; 7.1: Nozaki-Hiyama-Kishi reaction / 12.1: Swern oxidation;
DOI:10.1016/j.tet.2006.05.014