Technology Process of C50H94O8Si3
There total 10 articles about C50H94O8Si3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; dimethyl sulfoxide;
at 20 - 45 ℃;
for 3h;
DOI:10.1246/cl.2007.726
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: H2 / Pd(OH)2/C / dioxane / 3 h / 20 °C
2.1: PDC / CH2Cl2 / 3 h / 20 °C
3.1: PPh3; Et3N / CH2Cl2 / 0.17 h / -78 °C
4.1: 97 percent / n-BuLi / tetrahydrofuran / 2.5 h / -20 - 0 °C
5.1: Cp2ZrHCl / tetrahydrofuran / 24 h / 20 °C
5.2: 71 percent / I2 / tetrahydrofuran / 0.5 h / 20 °C
6.1: 90 percent / CrCl2 / NiCl2 / dimethylformamide / 3 h / 60 °C
7.1: 71 percent / IBX; pyridine / dimethylsulfoxide; tetrahydrofuran / 3 h / 20 - 45 °C
With
pyridine; chromium dichloride; dipyridinium dichromate; Schwartz's reagent; n-butyllithium; hydrogen; triethylamine; triphenylphosphine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
palladium dihydroxide; nickel dichloride;
In
tetrahydrofuran; 1,4-dioxane; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
4.1: Corey-Fuchs / 6.1: Noyaki-Hiyama-Kishi coupling;
DOI:10.1246/cl.2007.726
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 90 percent / CrCl2 / NiCl2 / dimethylformamide / 3 h / 60 °C
2: 71 percent / IBX; pyridine / dimethylsulfoxide; tetrahydrofuran / 3 h / 20 - 45 °C
With
pyridine; chromium dichloride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
nickel dichloride;
In
tetrahydrofuran; dimethyl sulfoxide; N,N-dimethyl-formamide;
1: Noyaki-Hiyama-Kishi coupling;
DOI:10.1246/cl.2007.726
