S-(n-dodecyl) 4-bromobenzothioate

Base Information

• Chemical Name: S-(n-dodecyl) 4-bromobenzothioate
• CAS No.: 94438-56-9
• Molecular Formula: C₁₉H₂₉BrOS
• Molecular Weight: 385.409
• Mol file: 94438-56-9.mol

Synonyms:S-(n-dodecyl) 4-bromobenzothioate

Chemical Property of S-(n-dodecyl) 4-bromobenzothioate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of S-(n-dodecyl) 4-bromobenzothioate

There total 5 articles about S-(n-dodecyl) 4-bromobenzothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

4-bromo-benzaldehyde (1122-91-4) + 1-dodecylthiol (112-55-0) → S-(n-dodecyl) 4-bromobenzothioate (94438-56-9)

Guidance literature:

With iron(II) bromide; tert-butyl alcohol; In water; at 110 ℃; for 1h; Reagent/catalyst; Schlenk technique; Inert atmosphere; Glovebox;

DOI:10.1021/jo500574p

Reference yield: 70.0%

didodecyl disulfide (2757-37-1) + 4-bromo-benzaldehyde (1122-91-4) → S-(n-dodecyl) 4-bromobenzothioate (94438-56-9)

Guidance literature:

With di-tert-butyl peroxide; In neat (no solvent); at 120 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c4gc00025k

Reference yield: 67.0%

didodecyl disulfide (2757-37-1) + para-bromotoluene (106-38-7) → S-(n-dodecyl) 4-bromobenzothioate (94438-56-9)

Guidance literature:

With di-tert-butyl peroxide; at 110 ℃; for 36h; Schlenk technique; Inert atmosphere;

DOI:10.1039/c4cc04503c

upstream raw materials:

ω-Azido-ω-dodecylmercapto-4-brom-acetophenon

4-Brom-ω-n-dodecylmercapto-acetophenon

4-bromo-benzaldehyde

1-dodecylthiol