{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

Base Information

Chemical Name:{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester
CAS No.:127980-39-6
Molecular Formula:C₁₈H₂₂O₄
Molecular Weight:302.37
Hs Code.:

Synonyms:{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of {3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

There total 2 articles about {3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127980-38-5
<1S-1α,2α,3α,4α>-3-<2-<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>ethyl>benzeneacetic acid, methyl ester

: 127980-39-6
{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

Guidance literature:: With Celite; sodium acetate; pyridinium chlorochromate; In dichloromethane; at 25 ℃; for 1.83333h;
DOI:10.1021/jm00113a030

Reference yield:

: 127980-37-4
{3-[2-((1S,2R,3R,4R)-3-Acetoxymethyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

: 127980-39-6
{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / potassium tert-butoxide / methanol / 2 h / 25 °C

2: pyridinium chlorochromate, Celite, NaOAc / CH₂Cl₂ / 1.83 h / 25 °C

With Celite; potassium tert-butylate; sodium acetate; pyridinium chlorochromate; In methanol; dichloromethane;
DOI:10.1021/jm00113a030

Reference yield:

: 127980-39-6
{3-[2-((1S,2R,3S,4R)-3-Formyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-ethyl]-phenyl}-acetic acid methyl ester

: 128051-35-4
<1S-1α,2α,3α,4α>-3-<2-<3-<<<(phenylamino)carbonyl>hydrazono>methyl>-7-oxabicyclo<2.2.1>hept-2-yl>ethyl>benzeneacetic acid

Guidance literature:: Multi-step reaction with 2 steps

1: methanol / 40 h / 25 °C

2: LiOH*H₂O / tetrahydrofuran; H₂O / 3 h / 25 °C

With lithium hydroxide; In tetrahydrofuran; methanol; water;
DOI:10.1021/jm00113a030