(E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate

Base Information

• Chemical Name: (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate
• CAS No.: 960505-56-0
• Molecular Formula: C₁₇H₁₃F₃O₄S
• Molecular Weight: 370.349
• Mol file: 960505-56-0.mol

Synonyms:(E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate

Chemical Property of (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate

There total 1 articles about (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

trifluoromethylsulfonic anhydride (358-23-6) + (E)-2'-hydroxy-3'-methylchalcone (73981-10-9) → (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate (960505-56-0)

Guidance literature:

With pyridine; at 0 - 20 ℃; for 12h;

DOI:10.1021/jo701741y

Reference yield:

(E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate (960505-56-0) → 4-methyl-(3R)-phenylindan-1-one + 4-methyl-(3S)-phenylindan-1-one

Guidance literature:

With Proton Sponge; palladium diacetate; In N,N-dimethyl-formamide; at 100 ℃; for 12h; Title compound not separated from byproducts.;

DOI:10.1021/jo701741y

Reference yield:

1,2,2,6,6-pentamethylpiperidine (79-55-0) + (E)-2-methyl-6-(3-phenylprop-2-enoyl)phenyl trifluoromethanesulfonate (960505-56-0) → 4-methyl-2-methylene-(3R)-phenylindan-1-one + 4-methyl-2-methylene-(3S)-phenylindan-1-one

Guidance literature:

With (R)-3,5-XylMeOBIPHEP; palladium diacetate; In 1,4-dioxane; at 100 ℃; for 12h; Title compound not separated from byproducts.;

DOI:10.1021/jo701741y

upstream raw materials:

trifluoromethylsulfonic anhydride

(E)-2'-hydroxy-3'-methylchalcone