ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

Base Information

Chemical Name:ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate
CAS No.:1434079-54-5
Molecular Formula:C₂₂H₁₈N₂O₃
Molecular Weight:358.397
Hs Code.:

Synonyms:ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

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Chemical Property of ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

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Technology Process of ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

There total 3 articles about ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1434079-39-6
ethyl 3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 1434079-54-5
ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

Guidance literature:: With trichlorophosphate; at 0 - 90 ℃; for 2h;
DOI:10.1016/j.tet.2013.04.034

Reference yield:

: 1434079-29-4
ethyl 3-acetyl-4-ethoxyazulene-1-carboxylate

: 1434079-54-5
ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: ethanol / 2 h / 20 °C

2: trichlorophosphate / 2 h / 0 - 90 °C

With trichlorophosphate; In ethanol; 2: |Vilsmeier-Haack Formylation;
DOI:10.1016/j.tet.2013.04.034

Reference yield:

: 128637-49-0
ethyl 4-ethoxyazulene-1-carboxylate

: 1434079-54-5
ethyl 4-formyl-3-methyl-2-phenyl-2H-azuleno[8,1-cd]pyridazine-5-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane / 2 h / 0 °C

2: ethanol / 2 h / 20 °C

3: trichlorophosphate / 2 h / 0 - 90 °C

With boron trifluoride diethyl etherate; trichlorophosphate; In ethanol; dichloromethane; 1: |Friedel-Crafts Acylation / 3: |Vilsmeier-Haack Formylation;
DOI:10.1016/j.tet.2013.04.034