isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Base Information

Chemical Name:isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside
CAS No.:1420236-15-2
Molecular Formula:C₆₄H₇₈N₄O₁₇
Molecular Weight:1175.34
Hs Code.:

isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Synonyms:isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Suppliers and Price of isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

There total 1 articles about isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1420235-80-8
isopropyl O-(2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranosyl)-(1→4)-O-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

: 1420236-15-2
isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Guidance literature:: isopropyl O-(2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranosyl)-(1→4)-O-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside; With triethylsilane; In dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve;

With phenylborondichloride; In dichloromethane; at -78 - -40 ℃; for 0.666667h; Inert atmosphere;
DOI:10.1002/chem.201202770

Reference yield: 72.0%

: 1420236-15-2
isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

: 1420236-23-2
isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(3-O-benzyl-α-L-idopyranosyluronic acid)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

Guidance literature:: isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside; With dihydrogen peroxide; lithium hydroxide; In tetrahydrofuran; water; at 0 - 20 ℃; for 48h;

With potassium hydroxide; In tetrahydrofuran; water; at 0 - 20 ℃; for 120h;
DOI:10.1002/chem.201202770

Reference yield:

: 1420236-15-2
isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl-3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside

: isopropyl O-(2-azido-2-deoxy-3,4-di-O-benzyl-6-O-sulfo-α-D-glucopyranosyl)-(1→4)-O-(3-O-benzyl-2-O-sulfo-α-L-idopyranosyluronic acid)-(1→4)-2-acetamido-2-deoxy-3,6-di-O-benzyl-α-D-glucopyranoside triethylammonium salt

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium hydroxide; dihydrogen peroxide / water; tetrahydrofuran / 48 h / 0 - 20 °C

1.2: 120 h / 0 - 20 °C

2.1: sulfur trioxide trimethylamine complex / N,N-dimethyl-formamide / 120 h / 50 °C / Inert atmosphere

2.2: 0.08 h / 20 °C / Inert atmosphere

With dihydrogen peroxide; sulfur trioxide trimethylamine complex; lithium hydroxide; In tetrahydrofuran; water; N,N-dimethyl-formamide;
DOI:10.1002/chem.201202770