endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene

Base Information

• Chemical Name: endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene
• CAS No.: 86318-27-6
• Molecular Formula: C₁₆H₁₆O₄
• Molecular Weight: 272.301

Synonyms:endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene

Chemical Property of endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene

There total 4 articles about endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

7-<4-(methoxycarbonyl)phenyl>-7-methyl-1,3,5-cycloheptatriene (86318-20-9) → endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.02,4>non-8-ene (86318-27-6)

Guidance literature:

With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane; at -20 ℃; for 3h; Irradiation;

Reference yield:

1-bromo-4-(cyclohepta-2,4,6-trien-1-yl)benzene (54615-31-5) → endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.02,4>non-8-ene (86318-27-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 43 percent / 15percent n-BuLi / diethyl ether; hexane / 0 °C

2: 1) KNH₂ / 1) ether, liquid NH₃, -33 deg C, 2) ether, liquid NH₃

3: 84 percent / diethyl ether / Ambient temperature

4: 54 percent / tetraphenylporphine, O₂ / CH₂Cl₂ / 3 h / -20 °C / Irradiation

With n-butyllithium; oxygen; 5,15,10,20-tetraphenylporphyrin; potassium amide; In diethyl ether; hexane; dichloromethane;

Reference yield:

4-(cyclohepta-2,4,6-trien-1-yl)benzoic acid (86318-22-1) → endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.02,4>non-8-ene (86318-27-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 1) KNH₂ / 1) ether, liquid NH₃, -33 deg C, 2) ether, liquid NH₃

2: 84 percent / diethyl ether / Ambient temperature

3: 54 percent / tetraphenylporphine, O₂ / CH₂Cl₂ / 3 h / -20 °C / Irradiation

With oxygen; 5,15,10,20-tetraphenylporphyrin; potassium amide; In diethyl ether; dichloromethane;

upstream raw materials:

7-<4-(methoxycarbonyl)phenyl>-7-methyl-1,3,5-cycloheptatriene

1-bromo-4-(cyclohepta-2,4,6-trien-1-yl)benzene

4-(cyclohepta-2,4,6-trien-1-yl)benzoic acid

7-(4-carboxyphenyl)-7-methyl-1,3,5-cycloheptatriene

Downstream raw materials:

anti,anti-9-<4-(methoxycarbonyl)phenyl>-9-methyl-3,6-dioxatetracyclo<6.1.0.0^2,4.0^5,7>nonane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 86318-27-6 endo-3-<4-(methoxycarbonyl)phenyl>-exo-3-methyl-6,7-dioxatricyclo<3.2.2.0^2,4>non-8-ene

Send

Send

Metric Ton KG G Pound L ML

Send

Send