(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

Base Information

Chemical Name:(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride
CAS No.:158180-33-7
Molecular Formula:C₃₄H₂₉ClP₂Ru
Molecular Weight:636.075
Hs Code.:

Synonyms:(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

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Chemical Property of (η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

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Technology Process of (η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

There total 1 articles about (η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: (η5-indenyl)ruthenium(bis(triphenylphosphine))chloride

: 2071-20-7
bis-diphenylphosphinomethane

: 158180-33-7
(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

Guidance literature:: In toluene; N2-atmosphere; refluxing (2 h); evapn. (vac.), chromy. (SiO2, CH2Cl2); elem. anal.;
DOI:10.1021/om950428k

Reference yield: 93.0%

: 158180-33-7
(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

: 140-92-1
potassium isopropylxanthate

: 1076225-04-1
(η2-1,1'-bis(diphenylphosphanyl)methane)(η2-S2COiPr)2 ruthenium(II)

Guidance literature:: In methanol; (N2 or Ar), 4 equiv. of ligand added to soln. of Ru complex in CH3OH, stirred at room temp. for 18 h; evapd., extd.(toluene), concd., treated with hexane, crystd. at -30°C for 1 d, elem. anal.;
DOI:10.1002/ejic.200700070

Reference yield: 90.0%

: sodium azide

: 158180-33-7
(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)ruthenium(II) chloride

: 867045-80-5
[(η5-indenyl)Ru(bis(diphenylphosphino)methane)(azide)]

Guidance literature:: In ethanol; byproducts: NaCl; to soln. of Ru complex in EtOH added NaN3; soln. was refluxed for 5 h; soln. was cooled to room temp.; solvent removed in rotary-evaporator; residue extd. (CH2Cl2); filtered; filtrate concd.; excess hexane added; solid was centrifuged; washed (hexane); elem. anal.;
DOI:10.1016/j.jorganchem.2005.06.016