1-(1-Bromovinyl)-4-chlorobenzene

Base Information

• Chemical Name: 1-(1-Bromovinyl)-4-chlorobenzene
• CAS No.: 89619-10-3
• Molecular Formula: C8H6 Br Cl
• Molecular Weight: 217.493
• Hs Code.: 2903999090
• European Community (EC) Number: 624-625-9
• DSSTox Substance ID: DTXSID70584862
• Nikkaji Number: J3.368.196H
• Wikidata: Q82476605
• Mol file: 89619-10-3.mol

Synonyms:1-(1-Bromovinyl)-4-chlorobenzene;89619-10-3;1-(1-BROMOETHENYL)-4-CHLOROBENZENE;Benzene, 1-(1-bromoethenyl)-4-chloro-;SCHEMBL6859878;DTXSID70584862;AKOS025295893;SY330891;1-(1-Bromovinyl)-4-chlorobenzene, 90%

Chemical Property of 1-(1-Bromovinyl)-4-chlorobenzene

Chemical Property:

• Vapor Pressure: 0.0171mmHg at 25°C
• Refractive Index: n20/D 1.605
• Boiling Point: 263.1°C at 760 mmHg
• Flash Point: 110 °C
• PSA: 0.00000
• Density: 1.539 g/mL at 25 °C
• LogP: 3.70560
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 215.93414
• Heavy Atom Count: 10
• Complexity: 125

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-(1-Bromovinyl)-4-chlorobenzene 90% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 22-37/38-41-51/53
• Safety Statements: 26-36/37/39-61

MSDS Files:

Useful:

• Canonical SMILES: C=C(C1=CC=C(C=C1)Cl)Br

Technology Process of 1-(1-Bromovinyl)-4-chlorobenzene

There total 11 articles about 1-(1-Bromovinyl)-4-chlorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,2-dibromo-1-(4-chlorophenyl)ethane (23135-16-2) → 1-(1-bromovinyl)-4-chlorobenzene (89619-10-3)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; methanol; at 20 ℃; for 16h;

DOI:10.1055/s-0036-1589143

Reference yield: 91.0%

1,1-dibromo-1-(4'-chlorophenyl)ethane → 1-(1-bromovinyl)-4-chlorobenzene (89619-10-3) + 4-chlorobenzoylmethyl bromide (536-38-9)

Guidance literature:

In N,N-dimethyl-formamide; at 90 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2018.01.047

Reference yield: 76.0%

4-n-chlorophenylacetylene (873-73-4) → 1-(1-bromovinyl)-4-chlorobenzene (89619-10-3)

Guidance literature:

With 1,1-dibromomethane; In N,N-dimethyl-aniline; at 120 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.tetlet.2014.06.070

upstream raw materials:

4-n-chlorophenylacetylene

3-chloro-α,β-dibromoethylbenzene

1,2-dibromo-1-(4-chlorophenyl)ethane

4-vinylbenzyl chloride

Downstream raw materials:

2-(4-chlorophenyl)-3-hydroxypropene

3-(4-chlorophenyl)-1,1,1-trifluorobut-3-en-2-ol

4,4'-(buta-1,3-diene-2,3-diyl)bis(chlorobenzene)

6-chloro-2-(4-chlorophenyl)-3-methyl-1H-indene