([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

Base Information

Chemical Name:([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium
CAS No.:945635-22-3
Molecular Formula:C₂₄H₃₄N₂O₃Pd
Molecular Weight:504.966
Hs Code.:

Synonyms:([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

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Chemical Property of ([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

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Technology Process of ([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

There total 2 articles about ([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 945635-20-1
(2-[(ethoxycarbonyl)methoxy]phenyl)iodo(N,N'-bis(cyclohexyl)ethylenediimine)palladium

: 945635-22-3
([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

Guidance literature:: With t-C₄H₉OK; In tetrahydrofuran; (Ar); injecting of t-BuOK in THF to soln. of PdI((CyNCH)2)(C6H4OCH2COOEt) in THF; stirring for 5 -15 min at room temp.; filtration through Celite and small plug of basic alumina with CH2Cl2 aseluent; removal solvent under reduced pressure, trituration with hexane and ethyl acetate mixt.;
DOI:10.1021/om7002865

Reference yield:

: 90794-32-4
2-([(ethoxycarbonyl)methylene]oxy)-1-iodobenzene

: 945635-22-3
([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

Guidance literature:: Multi-step reaction with 2 steps

1: benzene

2: t-C₄H₉OK / tetrahydrofuran

With t-C₄H₉OK; In tetrahydrofuran; benzene;
DOI:10.1021/om7002865

Reference yield: 95.0%

: 1117-71-1,56699-18-4,6000-00-6
methyl-4-bromo-2-butenoate

: 945635-22-3
([(ethoxycarbonyl)methineoxy]-1,2-phenylene)[N,N'-bis(cyclohexyl)ethylenediimine]palladium

: 945635-24-5
(1-(ethoxycarbonyl)-1-[2-(3-(methoxycarbonyl)-2-propenyl)phenoxy]methyl)bromo[N,N'-bis(cyclohexyl)ethylenediimine]palladium

Guidance literature:: In neat (no solvent); (Ar); stirring of suspn. of Pd((CyNCH)2)(C6H4OCHCOOEt) in methyl trans-4-bromo-2-butenoate for 30 min at 45°C; cooling to room temp., addn. of pentane; decanting of liquid; washing with pentane;
DOI:10.1021/om7002865