cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆

Base Information

• Chemical Name: cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆
• CAS No.: 89689-54-3
• Molecular Formula: C₃₉H₃₀ClN₂OOsP₂*F₆P
• Molecular Weight: 975.245
• Mol file: 89689-54-3.mol

Synonyms:cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆

Chemical Property of cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆

There total 2 articles about cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

ammonium hexafluorophosphate + cis-{Os(1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethylene)Cl2} (89689-85-0) → cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF6 (89689-54-3)

Guidance literature:

With carbon monoxide; In 2-methoxy-ethanol; Complex was allowed to react with a stream of CO while the soln. was heated to reflux for 30 min in 2-methoxyethanol; aq. NH4PF6 was added;; ppt. was filtered, washed with H2O, Et2O and dried;;

DOI:10.1021/om00086a016

Reference yield:

[Os(1,10-phenanthroline)Cl4] (89689-84-9) + cis-1,2-bis-(diphenylphosphino)ethene (983-80-2) → cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF6 (89689-54-3)

Guidance literature:

With carbon monoxide; In ethylene glycol; Complex was allowed to react with phosphine at reflux in ethylene glycol under an atm. of CO;;

DOI:10.1021/om00086a016

Reference yield:

cis-{Os(1,10-phenanthroline)(cis-1,2-bis(diphenylphosphino)ethylene)(CO)Cl}PF6 (89689-54-3) → Os(C12H8N2)((C6H5)2PC2H2P(C6H5)2)(P(C6H5)3)H(1+)*PF6(1-) (89689-68-9)

Guidance literature:

With triphenylphosphine; In ethylene glycol; byproducts: HCOCH2OH, CO, HCl; A soln. of complex in ethylene glycol was heated at reflux with PPh3;; chromy.;;

DOI:10.1021/om00086a016

upstream raw materials:

cis-{Os(1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethylene)Cl₂}

[Os(1,10-phenanthroline)Cl₄]

cis-1,2-bis-(diphenylphosphino)ethene

Downstream raw materials:

Os(C₁₂H₈N₂)((C₆H₅)2PC₂H₂P(C₆H₅)2)(P(C₂H₅)3)H⁽¹⁺⁾*PF₆^(1-)

Os(C₁₂H₈N₂)((C₆H₅)2PC₂H₂P(C₆H₅)2)(P(CH₃)2C₆H₅)Cl⁽¹⁺⁾*PF₆^(1-)

Os(C₁₂H₈N₂)((C₆H₅)2PC₂H₂P(C₆H₅)2)(P(C₆H₅)3)H⁽¹⁺⁾*PF₆^(1-)