S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

Base Information

Chemical Name:S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate
CAS No.:222973-52-6
Molecular Formula:C₂₉H₃₀O₄S₂
Molecular Weight:506.687
Hs Code.:

Synonyms:S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

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Chemical Property of S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

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Technology Process of S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

There total 1 articles about S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: S-methyl O-<(1S,4S,5R,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

: 222973-52-6
S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

Guidance literature:: In toluene; for 0.5h; Yield given; Heating;
DOI:10.1071/C97166

Reference yield: 86.0%

: 222973-52-6
S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

: 222973-53-7
(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-ene-1-thiol

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; methanol; for 0.416667h; Ambient temperature;
DOI:10.1071/C97166

Reference yield:

: 222973-52-6
S-methyl S-<(1R,4R,5S,6R)-4,5,6-tribenzyloxycyclohex-2-en-1-yl> dithiocarbonate

: (1R,2S,3R,6R)-6-((3R,4R,5R,6R)-4,5-Dihydroxy-6-methoxy-tetrahydro-pyran-3-ylsulfanyl)-cyclohex-4-ene-1,2,3-triol

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / aq. NaOH / tetrahydrofuran; methanol / 0.42 h / Ambient temperature

2: 72 percent / DBU / toluene / 6 h

3: NaOMe / methanol; tetrahydrofuran

4: 1) Na, 2) cation exchange resin Dowex 50W-X₂, H+ / 1) THF, NH₃ liq., -78 deg C, 2) H₂O

With sodium hydroxide; cation exchange resin Dowex 50W-X₂; sodium methylate; sodium; hydrogen cation; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol; toluene;
DOI:10.1071/C97166