((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

Base Information

Chemical Name:((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde
CAS No.:210702-68-4
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:

Synonyms:((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

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Chemical Property of ((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

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Technology Process of ((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

There total 4 articles about ((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 210702-67-3
(4S,5R)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane

: 210702-68-4
((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

Guidance literature:: With oxygen; copper(l) chloride; palladium dichloride; In water; N,N-dimethyl-formamide; at 60 ℃; for 18h;
DOI:10.1016/S0040-4039(98)00852-1

Reference yield:

: 922-65-6
divinylcarbinol

: 210702-68-4
((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 62 percent / D-(-)-DIPT, Ti(OiPr)4, 4 Angstroem mol. sieves / 2-methyl-propan-2-ol; CH₂Cl₂

2: 60 percent / Ti(OiPr)4 / 96 °C

3: 75 percent / CuSO₄, TsOH / Heating

4: 38 percent / PdCl₂, CuCl, O₂ / dimethylformamide; H₂O / 18 h / 60 °C

With titanium(IV) isopropylate; 4 A molecular sieve; oxygen; D-(-)-diisopropyl tartrate; toluene-4-sulfonic acid; copper(II) sulfate; copper(l) chloride; palladium dichloride; In dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1016/S0040-4039(98)00852-1

Reference yield:

: 102490-00-6
(2S,3R)-1,2-epoxy-4-penten-3-ol

: 210702-68-4
((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / Ti(OiPr)4 / 96 °C

2: 75 percent / CuSO₄, TsOH / Heating

3: 38 percent / PdCl₂, CuCl, O₂ / dimethylformamide; H₂O / 18 h / 60 °C

With titanium(IV) isopropylate; oxygen; toluene-4-sulfonic acid; copper(II) sulfate; copper(l) chloride; palladium dichloride; In water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)00852-1