9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine

Base Information

• Chemical Name: 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine
• CAS No.: 85421-90-5
• Molecular Formula: C₃₂H₂₂ClN₇O₁₃
• Molecular Weight: 748.019

Synonyms:9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine

Chemical Property of 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine

There total 2 articles about 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

6-chloro-9-trimethylsilylpurine (32865-86-4) + 6-deoxy-2,3,5-tris-O-(p-nitrobenzoyl)-D-allofuranosyl bromide (85505-01-7) → 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine (85421-90-5)

Guidance literature:

With mercury(II) cyanide; mercury dibromide; In 1,2-dichloro-ethane; Ambient temperature;

DOI:10.1021/jm00361a023

Reference yield:

6-chloropurine (87-42-3) → 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine (85421-90-5)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / benzene / 48 h

2: 85 percent / mercuric cyanide, mercuric bromide, / 1,2-dichloro-ethane / Ambient temperature

With mercury(II) cyanide; triethylamine; mercury dibromide; In 1,2-dichloro-ethane; benzene;

DOI:10.1021/jm00361a023

Reference yield: 100.0%

9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine (85421-90-5) → 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-thiopurine (85421-87-0)

Guidance literature:

With thiourea; In ethanol; for 4h; Heating;

DOI:10.1021/jm00361a023

upstream raw materials:

6-chloro-9-trimethylsilylpurine

6-deoxy-2,3,5-tris-O-(p-nitrobenzoyl)-D-allofuranosyl bromide

6-chloropurine

Downstream raw materials:

9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-thiopurine

9-(6-deoxy-β-D-allofuranosyl)hypoxanthine

9-(6'-deoxy-β-D-allofuranosyl)-6-thiopurine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 85421-90-5 9-<6'-deoxy-2',3',5'-tris-O-(p-nitrobenzoyl)-β-D-allofuranosyl>-6-chloropurine

Send

Send

Metric Ton KG G Pound L ML

Send

Send