(Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄)

Base Information

• Chemical Name: (Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄)
• CAS No.: 1224868-08-9
• Molecular Formula: C₄₈H₅₁P₂Rh₂S*ClO₄
• Molecular Weight: 1027.21

Synonyms:(Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄)

Chemical Property of (Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄)

Chemical Property:

Purity/Quality:

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Technology Process of (Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄)

There total 1 articles about (Rh₂(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + silver perchlorate + 2,6-bis[(diphenylphosphanyl)methyl]benzenethiol (235104-98-0) → (Rh2(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO4) (1224868-08-9)

Guidance literature:

With sodium hydride; In tetrahydrofuran; (N2 or Ar); addn. of NaH and (Rh(cod)Cl)2 to soln. of 2,6-bis((diphenylphosphanyl)methyl)benzenethiol in THF at 0°C; stirring for 4 h at room temp.; addn. of AgClO4; stirring for 1 h; filtration, washing with THF, removal of solvent under reduced pressure,chromy. on silica gel (hexane-ethyl acetate, 3:1 to ethyl acetate only) ; elem. anal.;

DOI:10.1021/om100067r

Reference yield:

(Rh2(1,5-cyclooctadiene)2[2,6-bis((diphenylphosphanyl)methyl)thiophenolate])(ClO4) (1224868-08-9) → rhodium (378784-00-0,7440-16-6)

Guidance literature:

With 1-(but-3-en-1-yl)naphthalene; hydrogen; In toluene; byproducts: 1-butylnaphthalene; under 1 atm of H2 to toluene soln. of 1-(but-3-en-1-yl)naphthalene addn.of (Rh2(COD)2((2,6-Ph2PCH2)2C6H3S))(ClO4); stirring at room temp. for 6 h; pptn.;

DOI:10.1021/om100067r

upstream raw materials:

2,6-bis[(diphenylphosphanyl)methyl]benzenethiol

Downstream raw materials:

rhodium

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