2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

Base Information

Chemical Name:2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime
CAS No.:73252-62-7
Molecular Formula:C₂₀H₂₁NO₇
Molecular Weight:387.389
Hs Code.:

Synonyms:2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

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Chemical Property of 2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

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Technology Process of 2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

There total 3 articles about 2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-(6-{6-[(Z)-Cyclohexyliminomethyl]-2,3,4-trimethoxy-phenyl}-benzo[1,3]dioxol-5-yl)-ethanone O-methyl-oxime

: 73252-62-7
2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

Guidance literature:: With hydrogenchloride; In dichloromethane; for 48h; Yield given;
DOI:10.1021/ja00522a058

Reference yield:

: 61599-79-9
1-(6-iodobenzo[d][1,3]dioxol-5-yl)ethan-1-one

: 73252-62-7
2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / 18 h / 25 °C

2: 1.) n-BuLi, 2.) CuI*P(OEt)3

3: 10percent aq. HCl / CH₂Cl₂ / 48 h

With pyridine; hydrogenchloride; n-butyllithium; triethylphosphite copper(I) iodide complex; In dichloromethane;
DOI:10.1021/ja00522a058

Reference yield:

: 73252-73-0
anti-2-iodo-4,5-methylenedioxyacetophenone O-methyl oxime

: 73252-62-7
2-acetyl-4,5-methylenedioxy-4',5',6'-trimethoxy-1,1'-biphenyl-2-carboxaldehyde anti-O-methyl oxime

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi, 2.) CuI*P(OEt)3

2: 10percent aq. HCl / CH₂Cl₂ / 48 h

With hydrogenchloride; n-butyllithium; triethylphosphite copper(I) iodide complex; In dichloromethane;
DOI:10.1021/ja00522a058