(μ-Se2)(carbonyl)6diiron

Base Information

• Chemical Name: (μ-Se2)(carbonyl)6diiron
• CAS No.: 76185-26-7
• Molecular Formula: C₆Fe₂O₆Se₂
• Molecular Weight: 437.676
• Mol file: 76185-26-7.mol

Synonyms:(μ-Se2)(carbonyl)6diiron

Chemical Property of (μ-Se2)(carbonyl)6diiron

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (μ-Se2)(carbonyl)6diiron

There total 2 articles about (μ-Se2)(carbonyl)6diiron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

diiron nonacarbonyl (15321-51-4) + 2-benzylidene-4-phenyl<2H(1,3-diselenole)> (15995-14-9) → (μ-Se2)(carbonyl)6diiron (76185-26-7) + (CO)6Fe2(μ-SeC(Ph)=C(H)Se)

Guidance literature:

In hexane; under N2, suspn. of educts in hexane stirred at room temp. for 24 h; evapd., dissolved in CH2Cl2/hexane, chromd. (Al2O3, hexane/CH2Cl2), recrystd. from hexane; elem. anal.;

Reference yield: 10.0%

diiron nonacarbonyl (15321-51-4) + 2,ω-distyryl-1,4-diselenafulvene (73214-45-6) → (μ-Se2)(carbonyl)6diiron (76185-26-7) + (SeC(CHCHC6H5)CHSe)Fe2(CO)6 (97353-05-4) + (OC)3Fe(SeC(CHCHC6H5)CHSe)Fe2(CO)6 (97374-12-4)

Guidance literature:

In hexane; under N2, suspn. of educts in hexane stirred at room temp. for 3 d; evapd., dissolved in CH2Cl2/hexane, chromd. (Al2O3, hexane/CH2Cl2), recrystd. from hexane; elem. anal.;

Reference yield: 99.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + (μ-Se2)(carbonyl)6diiron (76185-26-7) → Fe2(μ3-selenium)2(carbonyl)6Pt(triphenylphosphine)2

Guidance literature:

With methyl iodide; In benzene; byproducts: (CH3)(C6H5)3PI; under N2, to mixt. of Se2Fe2(CO)6 and CH3I in benzene was added (Ph3P)Pt, mixt. was stirred at room temp. overnight; silvent was removed, oil was chromd., recrystn. from CH2Cl2-pentane; elem. anal.;

DOI:10.1016/S0022-328X(00)80502-1

upstream raw materials:

diiron nonacarbonyl

2-benzylidene-4-phenyl<2H(1,3-diselenole)>

2,ω-distyryl-1,4-diselenafulvene

Downstream raw materials:

{Fe2Mo(μ3-Se2)(carbonyl)10}