ANILINE, p-BROMO-N-METHYL-N-NITROSO-

Base Information

• Chemical Name: ANILINE, p-BROMO-N-METHYL-N-NITROSO-
• CAS No.: 937-23-5
• Molecular Formula: C7H7 Br N2 O
• Molecular Weight: 215.049
• DSSTox Substance ID: DTXSID70239542
• Nikkaji Number: J579.801I
• Wikidata: Q83121918
• Mol file: 937-23-5.mol

Synonyms:ANILINE, p-BROMO-N-METHYL-N-NITROSO-;937-23-5;N-(4-bromophenyl)-N-methylnitrous amide;Benzenamine, 4-bromo-N-methyl-N-nitroso-;BRN 0639046;p-Bromo-N-methyl-N-nitrosoaniline;C7H7BrN2O;2-12-00-00354 (Beilstein Handbook Reference);DTXSID70239542;4-Bromo-N-methyl-N-nitrosoaniline;4-Bromo-N-methyl-N-nitroso-aniline;LS-19618;1-(4-bromophenyl)-1-methyl-2-oxohydrazine

Chemical Property of ANILINE, p-BROMO-N-METHYL-N-NITROSO-

Chemical Property:

• Vapor Pressure: 0.000221mmHg at 25°C
• Boiling Point: 326.1°C at 760 mmHg
• Flash Point: 151°C
• Density: 1.52g/cm³
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 213.97418
• Heavy Atom Count: 11
• Complexity: 134

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C1=CC=C(C=C1)Br)N=O

Technology Process of ANILINE, p-BROMO-N-METHYL-N-NITROSO-

There total 21 articles about ANILINE, p-BROMO-N-METHYL-N-NITROSO- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-bromo-N-methylaniline (6911-87-1,211060-12-7) → 4-bromo-N-nitroso-N-methylaniline (937-23-5)

Guidance literature:

With sodium azide; In water; acetonitrile; at 20 ℃;

DOI:10.1039/c4cc07440h

Reference yield: 93.0%

4-bromo-N,N-dimethylaniline (586-77-6) → 4-bromo-N-nitroso-N-methylaniline (937-23-5)

Guidance literature:

With tert.-butylnitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; In acetonitrile; at 20 ℃; for 0.5h; Reagent/catalyst; Solvent; Temperature; Mechanism;

DOI:10.1039/c7gc02775c

Reference yield: 88.0%

4-bromo-N,N-dimethylaniline (586-77-6) → di-n-butyloxymethane (2568-90-3) + 4-bromo-N-nitroso-N-methylaniline (937-23-5)

Guidance literature:

With n-Butyl nitrite; water; ammonium chloride; for 0.25h; Heating;

DOI:10.1016/S0040-4020(01)86768-5

upstream raw materials:

tetranitromethane

4-bromo-N,N-dimethylaniline

N-methyl-N-nitrosoaniline

4-bromo-N-methylaniline

Downstream raw materials:

N-(4-bromo-phenyl)-N-methylacetamide

4-bromo-N-methylaniline

1-(4-bromophenyl)-1-methylhydrazine

D-arabino-[2]hexosulose-bis-[(4-bromo-phenyl)-methyl-hydrazone]