(2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester

Base Information

• Chemical Name: (2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester
• CAS No.: 112374-17-1
• Molecular Formula: C₁₈H₂₀O₇
• Molecular Weight: 348.353
• Mol file: 112374-17-1.mol

Synonyms:(2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester

Chemical Property of (2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester

There total 1 articles about (2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl 2-(3-methoxybenzylidene)malonate (22621-56-3) + 2-<(trimethylsilyl)methyl>-3-(trimethylsilyl)prop-2-en-1-yl methyl carbonate (112373-93-0) → (2S,3S)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester (112374-18-2) + (2S,3R)-2-(3-Methoxy-phenyl)-4-methylene-cyclopentane-1,1,3-tricarboxylic acid dimethyl ester (112374-17-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 80 ℃; for 8h; Yield given. Yields of byproduct given;

DOI:10.1021/ja00213a038

upstream raw materials:

dimethyl 2-(3-methoxybenzylidene)malonate

2-<(trimethylsilyl)methyl>-3-(trimethylsilyl)prop-2-en-1-yl methyl carbonate