Technology Process of diisobutyl (2E,2'E)-3,3'-[5-(3,5-dimethylphenyl)thiophene-2,3-diyl]diacrylate
There total 2 articles about diisobutyl (2E,2'E)-3,3'-[5-(3,5-dimethylphenyl)thiophene-2,3-diyl]diacrylate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
palladium diacetate; triethylamine; tricyclohexylphosphine;
In
N,N-dimethyl-formamide;
at 100 ℃;
for 24h;
Inert atmosphere;
DOI:10.1016/j.tet.2012.10.050
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / 1,4-dioxane; toluene / 12 h / 100 °C
2: triethylamine; tricyclohexylphosphine; palladium diacetate / N,N-dimethyl-formamide / 24 h / 100 °C / Inert atmosphere
With
tetrakis(triphenylphosphine) palladium(0); palladium diacetate; potassium carbonate; triethylamine; tricyclohexylphosphine;
In
1,4-dioxane; N,N-dimethyl-formamide; toluene;
1: |Suzuki-Miyaura Coupling / 2: |Heck Reaction;
DOI:10.1016/j.tet.2012.10.050
- Guidance literature:
-
diisobutyl (2E,2'E)-3,3'-[5-(3,5-dimethylphenyl)thiophene-2,3-diyl]diacrylate;
In
diphenylether;
at 200 ℃;
for 24h;
With
10 mol% palladium on carbon;
In
diphenylether;
at 200 ℃;
for 48h;
Inert atmosphere;
DOI:10.1016/j.tet.2012.10.050
