benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

Base Information

Chemical Name:benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside
CAS No.:120046-94-8
Molecular Formula:C₁₆H₂₂O₄
Molecular Weight:278.348
Hs Code.:

Synonyms:benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

Chemical Property:

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Technology Process of benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

There total 3 articles about benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: oleandomycin hydrochloride

: 120046-94-8
benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) 20 percent NaOH, 2.) 1 percent hydrochloric acid, 3.) molecular sieves 3 Angstroem, 4.) pyridinium chlorochromate

2: 1.) diisopropylamide, 3.) potassium hydride / 1.) THF, 0 deg C, 2.) THF, -78 deg C -> room temperature, 3.) N,N'-dimethylformamide, 1 h

With hydrogenchloride; sodium hydroxide; 3 A molecular sieve; potassium hydride; diisopropylamine; pyridinium chlorochromate;
DOI:10.1016/S0040-4020(01)87245-8

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 120046-94-8
benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) 20 percent NaOH, 2.) 1 percent hydrochloric acid, 3.) molecular sieves 3 Angstroem, 4.) pyridinium chlorochromate

2: 1.) diisopropylamide, 3.) potassium hydride / 1.) THF, 0 deg C, 2.) THF, -78 deg C -> room temperature, 3.) N,N'-dimethylformamide, 1 h

With hydrogenchloride; sodium hydroxide; 3 A molecular sieve; potassium hydride; diisopropylamine; pyridinium chlorochromate;
DOI:10.1016/S0040-4020(01)87245-8

Reference yield:

: 153185-49-0
(2S,4S,6R)-6-Benzyloxy-4-methoxy-2-methyl-dihydro-pyran-3-one

: 4455-77-0
(methoxymethyl)diphenylphosphine oxide

: 120046-94-8
benzyl 2,4,6-trideoxy-3-O-methyl-4-C-methoxymethylene-α-L-threo-hexopyranoside

Guidance literature:: With potassium hydride; diisopropylamine; Yield given. Multistep reaction; 1.) THF, 0 deg C, 2.) THF, -78 deg C -> room temperature, 3.) N,N'-dimethylformamide, 1 h;
DOI:10.1016/S0040-4020(01)87245-8