1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide

Base Information

• Chemical Name: 1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide
• CAS No.: 1328936-48-6
• Molecular Formula: C₂₁H₂₁N₄S*I
• Molecular Weight: 488.395
• Mol file: 1328936-48-6.mol

Synonyms:1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide

Chemical Property of 1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide

Chemical Property:

Purity/Quality:

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Technology Process of 1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide

There total 1 articles about 1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1,1'-methylene-bis(3-benzyl-1H-imidazol-3-ium) diiodide → 1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide (1328936-48-6)

Guidance literature:

With sulfur; potassium carbonate; In methanol; for 20h; Reflux;

DOI:10.1021/om200629j

Reference yield: 63.0%

1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide (1328936-48-6) + silver(l) oxide (20667-12-3) → iodido{1-(3-benzyl-2H-imidazol-1-yl-2-thione)-methyl-3-benzyl-2H-imidazol-2-ylidene}silver(I)

Guidance literature:

In dichloromethane; at 40 ℃; for 24h; Inert atmosphere;

DOI:10.1021/om300615e

Reference yield: 55.0%

1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazolium) iodide (1328936-48-6) + copper (I) acetate (598-54-9,142-71-2,4180-12-5,24381-58-6,66760-61-0,66760-62-1) → [Cu(1,1'-methylene(3-benzyl-2H-imidazole-2-thione)(3-benzylimidazol-2-ylidene))I]2

Guidance literature:

In acetonitrile; (N2) to suspn. AcOCu in MeCN imidazolium salt was added, stirred at roomtemp. for 18 h; soln. was filtered and concd., Et2O was added, ppt. was filtered off; elem. anal.;

DOI:10.1021/om200629j