methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside
CAS No.:1353896-04-4
Molecular Formula:C₁₈H₂₀N₂O₈
Molecular Weight:392.365
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Suppliers and Price of methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

There total 2 articles about methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₈H₂₁BrO₈

: 1353896-04-4
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Guidance literature:: With N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 0 ℃; Inert atmosphere;
DOI:10.1080/07328303.2011.614983

Reference yield:

: 2872-56-2,18031-57-7,20750-03-2,37180-50-0,37180-54-4,87924-30-9,96779-62-3,104321-10-0,141611-59-8,144607-25-0,144607-28-3,150654-17-4,130464-35-6
3-O-acetyl-(4,6-O-benzylidene)methyl-α-D-mannopyranoside

: 1353896-04-4
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / chloroform / 2 h / 0 °C / Inert atmosphere

2: N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 0 °C / Inert atmosphere

With pyridine; N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; chloroform;
DOI:10.1055/s-0032-1317013

Reference yield: 90.0%

: 1353896-04-4
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-acetyl-α-D-mannopyranoside

: 1423010-15-4
(2R,4aR,5aS,8aS,9S,9aR)-5a-methoxy-7-oxo-2-phenyloctahydrofuro[2',3':5,6]pyrano[3,2-d][1,3]dioxin-9-yl acetate

Guidance literature:: With dirhodium tetraacetate; In 1,2-dichloro-ethane; Concentration; Molecular sieve; Reflux; Inert atmosphere;
DOI:10.1055/s-0032-1317013