[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

Base Information

Chemical Name:[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]
CAS No.:1116154-59-6
Molecular Formula:C₃₂H₂₁ClF₁₂I₂NNiOP
Molecular Weight:1042.43
Hs Code.:

Synonyms:[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

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Chemical Property of [(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

Chemical Property:

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Technology Process of [(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

There total 1 articles about [(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 667938-70-7
[(2,6-(3,5-(CF₃)2C₆H₃)2-4-yl-C₆H₃)NCH(3,5-I₂-2-OH-C₆H₂)]

: 20087-67-6
dichlorobis(trimethylphosphine)nickel

: 1116154-59-6
[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

Guidance literature:: With triethylamine; In toluene; under Ar atm. to soln. Ni complex and Et3N in toluene soln. ligand in toluene was added dropwise; solvent was removed in vacuo, residue was dissolved in mixt. pentane andtoluene (1:1), filtered and evapd. in vacuo, residue was treated with c old MeOH, ppt. was filtered under Ar atm.;

Reference yield: 35.0%

: 1116154-59-6
[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

: sodium trimethoxyborohydride

: 1116154-57-4
[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(H)(PMe3)]

Guidance literature:: In tetrahydrofuran; diethyl ether; under Ar atm. to mixt. Ni complex and Na(HB(OMe)3) mixt. Et2O and THF was added at -60°C and stirred at -10°C for 2 h; solvent was removed in vacuo, residue was dissolved in cold ether (-60°C), stirred at -60°C for 15 min, filtered through diatomaceous earth, solvent was removed in vacuo at -10°C;

Reference yield:

: 1116154-59-6
[(κ2-N,O-(2,6-(3,5-(F3C)2C6H3)2C6H3)-N=CH-(3,5-I2-2-OC6H2))Ni(Cl)(PMe3)]

: [(κ-((2,6-(3,5-(CF3)2C6H3)2C6H3)-N=C(H)-(3,5-I2-2-O-C6H2))Ni(CH2CH3)(PMe3)]

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran; diethyl ether

2: tetrahydrofuran

3: tetrahydrofuran-d8

In tetrahydrofuran; tetrahydrofuran-d8; diethyl ether;
DOI:10.1021/ja901360b