10,10'-bis(3-fluorophenyl)-9,9'-bianthracene

Base Information

• Chemical Name: 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene
• CAS No.: 1505455-96-8
• Molecular Formula: C₄₀H₂₄F₂
• Molecular Weight: 542.627
• Mol file: 1505455-96-8.mol

Synonyms:10,10'-bis(3-fluorophenyl)-9,9'-bianthracene

Chemical Property of 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene

There total 3 articles about 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

10,10'-dibromo-9,9'-bianthryl (121848-75-7) + 3-fluorophenylboronic acid (768-35-4) → 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene (1505455-96-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; water; potassium carbonate; In tetrahydrofuran; for 24h; Inert atmosphere; Reflux;

DOI:10.1039/c3tc31743a

Reference yield:

9,10-phenanthrenequinone (84-65-1) → 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene (1505455-96-8)

Guidance literature:

Multi-step reaction with 3 steps

1: zinc; hydrogenchloride; acetic acid

2: bromine / 1,2-dichloro-ethane

3: water; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; water; bromine; potassium carbonate; acetic acid; zinc; In tetrahydrofuran; 1,2-dichloro-ethane; 3: |Suzuki Coupling;

DOI:10.1039/c3tc31743a

Reference yield:

9,9'-bianthracene (1055-23-8) → 10,10'-bis(3-fluorophenyl)-9,9'-bianthracene (1505455-96-8)

Guidance literature:

Multi-step reaction with 2 steps

1: bromine / 1,2-dichloro-ethane

2: water; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; water; bromine; potassium carbonate; In tetrahydrofuran; 1,2-dichloro-ethane; 2: |Suzuki Coupling;

DOI:10.1039/c3tc31743a

upstream raw materials:

10,10'-dibromo-9,9'-bianthryl

3-fluorophenylboronic acid

9,10-phenanthrenequinone

9,9'-bianthracene

Refernces