(4-chlorobenzyl)(triphenyl)-lambda~5~-arsanyl

Base Information

• Chemical Name: (4-chlorobenzyl)(triphenyl)-lambda~5~-arsanyl
• CAS No.: 60430-77-5
• Molecular Formula: C25H21 As Cl . Br
• Molecular Weight: 511.72
• Mol file: 60430-77-5.mol

Synonyms:Arsonium,[(4-chlorophenyl)methyl]triphenyl-, bromide (9CI); NSC 131512

Chemical Property of (4-chlorobenzyl)(triphenyl)-lambda~5~-arsanyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (4-chlorobenzyl)(triphenyl)-lambda~5~-arsanyl

There total 1 articles about (4-chlorobenzyl)(triphenyl)-lambda~5~-arsanyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenyl-arsane (603-32-7) + 4-chlorobenzyl bromide (622-95-7) → (p-chlorobenzyl)triphenylarsonium bromide (60430-77-5)

Guidance literature:

In chloroform;

Reference yield: 82.0%

(E)-1,3-diphenyl-2-trifluoromethylsulfonylprop-2-en-1-one + (p-chlorobenzyl)triphenylarsonium bromide (60430-77-5) → 2-(4-chlorophenyl)-3,5-diphenyl-4-trifluoromethylsulfonyl-cis-2,3-dihydrofuran + 2-(4-chlorophenyl)-3,5-diphenyl-4-trifluoromethylsulfonyl-trans-2,3-dihydrofuran

Guidance literature:

With caesium carbonate; In dichloromethane; for 1.5h; stereoselective reaction; Reflux;

DOI:10.1016/j.tet.2010.05.097

Reference yield: 78.0%

(E)-3-(2-furyl)-2-trifluoromethylsulfonyl-1-phenylprop-2-en-1-one (1239702-01-2) + (p-chlorobenzyl)triphenylarsonium bromide (60430-77-5) → 2-(4-chlorophenyl)-3-(2-furyl)-4-trifluoromethylsulfonyl-5-phenyl-cis-2,3-dihydrofuran + 2-(4-chlorophenyl)-3-(2-furyl)-4-trifluoromethylsulfonyl-5-phenyl-trans-2,3-dihydrofuran

Guidance literature:

With caesium carbonate; In dichloromethane; for 0.5h; stereoselective reaction; Reflux;

DOI:10.1016/j.tet.2010.05.097

upstream raw materials:

triphenyl-arsane

4-chlorobenzyl bromide

Downstream raw materials:

9-(4-chlorobenzylidene)-9H-fluorene

triphenylarsineoxide

(4-Chloro-benzylidene)-triphenyl-λ⁵-arsane

trans-1-(4-chlorophenyl)-2-(9-anthryl)ethene