4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

Base Information

• Chemical Name: 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol
• CAS No.: 264626-96-2
• Molecular Formula: C₃₆H₅₁N₁₅O₁₀S
• Molecular Weight: 885.961

Synonyms:4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

Chemical Property of 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

There total 14 articles about 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

phenyl [[[[(3-azido-2,3-dideoxy-4-trimethylsilyl-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-3-azido-2,3-dideoxy-1-thio-α-... (264626-95-1) → 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol (264626-96-2)

Guidance literature:

With pyridine hydrogenfluoride; In tetrahydrofuran; for 1h;

DOI:10.1021/ja992513f

Reference yield:

4-O-acetyl-3-azido-2,3,6-trideoxy-L-ribo-hexopyranose → 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol (264626-96-2)

Guidance literature:

Multi-step reaction with 12 steps

1: pyridine; DMAP / 0.33 h / 20 °C

2: BF₃*Et₂O / CH₂Cl₂ / 0.33 h / 20 °C

3: K₂CO₃ / methanol / 2 h / 20 °C

4: pyridine / CH₂Cl₂ / 1 h

5: 18-crown-6 / dimethylformamide / 4 h

6: LiOH / methanol

7: Et₃N / CH₂Cl₂ / 0.33 h / -78 °C

8: mCPBA / CH₂Cl₂ / -42 °C

9: 21 percent / 2,6-di-tert-butyl-4-methylpyridine; 4 Angstroem molecular sieves; triflic anhydride / toluene; CH₂Cl₂ / 0.25 h / -78 °C

10: 95 percent / pyridinium hydrofluoride / tetrahydrofuran

11: 74 percent / triflic anhydride; 4 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.25 h / -78 °C

12: 90 percent / pyridinium hydrofluoride / tetrahydrofuran / 1 h

With pyridine; dmap; lithium hydroxide; 2,6-di-tert-butyl-4-methylpyridine; 18-crown-6 ether; trifluoromethylsulfonic anhydride; 4 A molecular sieve; boron trifluoride diethyl etherate; potassium carbonate; pyridine hydrogenfluoride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 1: Acetylation / 2: Substitution / 3: Hydrolysis / 4: sulphonation / 5: Esterification / 6: Hydrolysis / 7: silylation / 8: Oxidation / 9: Condensation / 10: desilylation / 11: Condensation / 12: desilylation;

DOI:10.1021/ja992513f

Reference yield:

(2S,3R,4S,6S)-4-Azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-ol (283170-20-7) → 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol (264626-96-2)

Guidance literature:

Multi-step reaction with 9 steps

1: pyridine / CH₂Cl₂ / 1 h

2: 18-crown-6 / dimethylformamide / 4 h

3: LiOH / methanol

4: Et₃N / CH₂Cl₂ / 0.33 h / -78 °C

5: mCPBA / CH₂Cl₂ / -42 °C

6: 21 percent / 2,6-di-tert-butyl-4-methylpyridine; 4 Angstroem molecular sieves; triflic anhydride / toluene; CH₂Cl₂ / 0.25 h / -78 °C

7: 95 percent / pyridinium hydrofluoride / tetrahydrofuran

8: 74 percent / triflic anhydride; 4 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.25 h / -78 °C

9: 90 percent / pyridinium hydrofluoride / tetrahydrofuran / 1 h

With pyridine; lithium hydroxide; 2,6-di-tert-butyl-4-methylpyridine; 18-crown-6 ether; trifluoromethylsulfonic anhydride; 4 A molecular sieve; pyridine hydrogenfluoride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 1: sulphonation / 2: Esterification / 3: Hydrolysis / 4: silylation / 5: Oxidation / 6: Condensation / 7: desilylation / 8: Condensation / 9: desilylation;

DOI:10.1021/ja992513f

upstream raw materials:

phenyl [[[[(3-azido-2,3-dideoxy-4-trimethylsilyl-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-3-azido-2,3-dideoxy-1-thio-α-...

(2S,3S,4S,6S)-4-Azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-ol

(2S,3R,4S,6S)-4-Azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-ol

1,4-di-O-acetyl-3-azido-2,3,6-trideoxy-L-arabino-hexopyranose

Downstream raw materials:

C₃₇H₅₃N₁₅O₁₀S

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 264626-96-2 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

Send

Send

Metric Ton KG G Pound L ML

Send

Send