1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

Base Information

Chemical Name:1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide
CAS No.:1027887-51-9
Molecular Formula:C₂₄H₃₀N₂O₄Si
Molecular Weight:438.599
Hs Code.:

Synonyms:1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

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Chemical Property of 1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

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Technology Process of 1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

There total 4 articles about 1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 155820-15-8
1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane

: 1027887-51-9
1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1021/jo00087a012

Reference yield:

: 19437-26-4
2,2'-dipyridyl ketone

: 1027887-51-9
1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Mg, BrCH₂CH₂Br / 1.) THF, 2.) THF, r.t., 16 h

2: 71 percent / NaH / tetrahydrofuran / 1.) r.t., 1 h, 2.) r.t., 15 h

3: 86 percent / m-CPBA / CH₂Cl₂ / 48 h / Ambient temperature

With sodium hydride; magnesium; ethylene dibromide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00087a012

Reference yield:

: 65423-56-5
1-bromo-3-[(tert-butyldimethylsilyl)oxy]benzene

: 1027887-51-9
1,1-Di(2-pyridyl)-1-methoxy-1-<3-<(tert-butyldimethylsilyl)oxy>phenyl>methane N,N'-dioxide

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Mg, BrCH₂CH₂Br / 1.) THF, 2.) THF, r.t., 16 h

2: 71 percent / NaH / tetrahydrofuran / 1.) r.t., 1 h, 2.) r.t., 15 h

3: 86 percent / m-CPBA / CH₂Cl₂ / 48 h / Ambient temperature

With sodium hydride; magnesium; ethylene dibromide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00087a012