(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

Base Information

Chemical Name:(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde
CAS No.:124177-06-6
Molecular Formula:C₁₅H₂₈O₂Si
Molecular Weight:268.472
Hs Code.:

Synonyms:(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

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Chemical Property of (S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

Chemical Property:

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Technology Process of (S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

There total 4 articles about (S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 124177-05-5,124263-00-9
(S)-3-(tert-Butyl-dimethyl-silanyloxy)-6-[1-butylsulfanyl-meth-(Z)-ylidene]-2,2-dimethyl-cyclohexanol

: 124177-06-6
(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

Guidance literature:: With cadmium(II) carbonate; mercury dichloride; In ethanol; for 0.05h; Yield given; Heating;

Reference yield:

: 106540-31-2
(+)-(S)-3-(tert-butyldimethylsiloxy)-2,2-dimethylcyclohexanone

: 124177-06-6
(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) sodium hydride / 1.) THF, benzene, 10 min 2.) ca. 12 h, room temperature

2: p-toluenesulfonic acid / benzene / 2 h / Heating

3: NaBH₄ / aq. ethanol; tetrahydrofuran / 1.5 h / 0 - 4 °C

4: cadmium carbonate, mercuric chloride / aq. ethanol / 0.05 h / Heating

With sodium tetrahydroborate; cadmium(II) carbonate; sodium hydride; toluene-4-sulfonic acid; mercury dichloride; In tetrahydrofuran; ethanol; benzene;

Reference yield:

: 124177-03-3
(S)-3-(tert-butyldimethylsilyloxy)-6-formyl-2,2-dimethylcyclohexanone

: 124177-06-6
(S)-4-(tert-butyldimethylsilyloxy)-3,3-dimethyl-1-cyclohexenecarbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: p-toluenesulfonic acid / benzene / 2 h / Heating

2: NaBH₄ / aq. ethanol; tetrahydrofuran / 1.5 h / 0 - 4 °C

3: cadmium carbonate, mercuric chloride / aq. ethanol / 0.05 h / Heating

With sodium tetrahydroborate; cadmium(II) carbonate; toluene-4-sulfonic acid; mercury dichloride; In tetrahydrofuran; ethanol; benzene;